On the product rotational state distribution in exoergic atom-diatomic molecule reactions

R. D. Levine; B. R. Johnson; R. B. Bernstein

doi:10.1016/0009-2614(73)87048-4

On the product rotational state distribution in exoergic atom-diatomic molecule reactions

R. D. Levine^*, B. R. Johnson, R. B. Bernstein

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

70 Scopus citations

Abstract

Product rotational state distributions (measured by Polanyi et al. via IR chemiluminescence) for the reactions Cl + HI/DI, F + H₂/D₂ and H/D + Cl₂ are governed by the fraction of the total energy available for product rotational excitation. The distribution of final rotational states can be characterized by a temperature parameter which is independent of the vibrational state and is isotopically invariant.

Original language	English
Pages (from-to)	1-6
Number of pages	6
Journal	Chemical Physics Letters
Volume	19
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(73)87048-4
State	Published - 1973
Externally published	Yes

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title = "On the product rotational state distribution in exoergic atom-diatomic molecule reactions",

abstract = "Product rotational state distributions (measured by Polanyi et al. via IR chemiluminescence) for the reactions Cl + HI/DI, F + H2/D2 and H/D + Cl2 are governed by the fraction of the total energy available for product rotational excitation. The distribution of final rotational states can be characterized by a temperature parameter which is independent of the vibrational state and is isotopically invariant.",

author = "Levine, \{R. D.\} and Johnson, \{B. R.\} and Bernstein, \{R. B.\}",

year = "1973",

doi = "10.1016/0009-2614(73)87048-4",

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AU - Levine, R. D.

AU - Johnson, B. R.

AU - Bernstein, R. B.

PY - 1973

Y1 - 1973

N2 - Product rotational state distributions (measured by Polanyi et al. via IR chemiluminescence) for the reactions Cl + HI/DI, F + H2/D2 and H/D + Cl2 are governed by the fraction of the total energy available for product rotational excitation. The distribution of final rotational states can be characterized by a temperature parameter which is independent of the vibrational state and is isotopically invariant.

AB - Product rotational state distributions (measured by Polanyi et al. via IR chemiluminescence) for the reactions Cl + HI/DI, F + H2/D2 and H/D + Cl2 are governed by the fraction of the total energy available for product rotational excitation. The distribution of final rotational states can be characterized by a temperature parameter which is independent of the vibrational state and is isotopically invariant.

UR - https://www.scopus.com/pages/publications/33847052064

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JO - Chemical Physics Letters

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On the product rotational state distribution in exoergic atom-diatomic molecule reactions

Abstract

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