On the reactivity-selectivity relationship in the solvolysis of several reactive alkyl halides

Rachel Ta-Shma; Zvi Rappoport

doi:10.1016/S0040-4039(00)86948-8

On the reactivity-selectivity relationship in the solvolysis of several reactive alkyl halides

Rachel Ta-Shma^*
, Zvi Rappoport

^*Corresponding author for this work

School of Pharmacy

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

In contrast to previous reports, the selectivities of four carbenium ions R⁺ towards N₃^- and H₂O (log(K_N₃^-/K_H₂O)) change more than the solvolytic reactivities (log K_solv) of their rather reactive precursors RCl.

Original language	English
Pages (from-to)	781-784
Number of pages	4
Journal	Tetrahedron Letters
Volume	23
Issue number	7
DOIs	https://doi.org/10.1016/S0040-4039(00)86948-8
State	Published - 1982

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title = "On the reactivity-selectivity relationship in the solvolysis of several reactive alkyl halides",

abstract = "In contrast to previous reports, the selectivities of four carbenium ions R+ towards N3- and H2O (log(KN3-/KH2O)) change more than the solvolytic reactivities (log Ksolv) of their rather reactive precursors RCl.",

author = "Rachel Ta-Shma and Zvi Rappoport",

year = "1982",

doi = "10.1016/S0040-4039(00)86948-8",

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AU - Ta-Shma, Rachel

AU - Rappoport, Zvi

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AB - In contrast to previous reports, the selectivities of four carbenium ions R+ towards N3- and H2O (log(KN3-/KH2O)) change more than the solvolytic reactivities (log Ksolv) of their rather reactive precursors RCl.

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 7

ER -

On the reactivity-selectivity relationship in the solvolysis of several reactive alkyl halides

Abstract

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