TY - JOUR
T1 - One-pot sequences of reactions with sol-gel entrapped opposing reagents. Oxidations and catalytic reductions
AU - Gelman, Faina
AU - Blum, Jochanan
AU - Avnir, David
PY - 2003/2/1
Y1 - 2003/2/1
N2 - An oxidant and a reducing catalyst are placed in a single pot without destroying each other, but are still capable of carrying out useful reactions, simultaneously. The oxidant, pyridinium dichromate, and an H2-reduction catalyst, RhCl[P(C6H5)3]3, were entrapped in separate sol-gel matrices, and with these entrapped reagent and catalyst, three different flow-chart sequences of one-pot redox reactions were carried out - up to four reactions in one pot - without their mutual destruction and with no need for separation steps.
AB - An oxidant and a reducing catalyst are placed in a single pot without destroying each other, but are still capable of carrying out useful reactions, simultaneously. The oxidant, pyridinium dichromate, and an H2-reduction catalyst, RhCl[P(C6H5)3]3, were entrapped in separate sol-gel matrices, and with these entrapped reagent and catalyst, three different flow-chart sequences of one-pot redox reactions were carried out - up to four reactions in one pot - without their mutual destruction and with no need for separation steps.
UR - http://www.scopus.com/inward/record.url?scp=0037295536&partnerID=8YFLogxK
U2 - 10.1039/b208043p
DO - 10.1039/b208043p
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AN - SCOPUS:0037295536
SN - 1144-0546
VL - 27
SP - 205
EP - 207
JO - New Journal of Chemistry
JF - New Journal of Chemistry
IS - 2
ER -