OOxidative bromination of activated aromatic compounds using aqueous nitric acid as an oxidant

Ashutosh V. Joshi; Mubeen Baidossi; Sudip Mukhopadhyay; Yoel Sasson

doi:10.1021/op030055w

OOxidative bromination of activated aromatic compounds using aqueous nitric acid as an oxidant

Ashutosh V. Joshi
, Mubeen Baidossi
, Sudip Mukhopadhyay^*
, Yoel Sasson

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

43 Scopus citations

Abstract

Oxidative bromination of activated aromatic compounds using alkali metal bromide salts and aqueous nitric acid to the corresponding bromo-derivatives is achieved in a liquid-liquid, two-phase system under ambient conditions. Nitric acid offers a dual function of an oxidant as well as a proton donor, which is essential for oxidative bromination using metal bromide salts. Bromination as well as chlorination could be accomplished with this simple system.

Original language	English
Pages (from-to)	568-570
Number of pages	3
Journal	Organic Process Research and Development
Volume	8
Issue number	4
DOIs	https://doi.org/10.1021/op030055w
State	Published - Jul 2004

Access to Document

10.1021/op030055w

Cite this

@article{5f19ad1b0d11480ba9820043eaa0a413,

title = "OOxidative bromination of activated aromatic compounds using aqueous nitric acid as an oxidant",

abstract = "Oxidative bromination of activated aromatic compounds using alkali metal bromide salts and aqueous nitric acid to the corresponding bromo-derivatives is achieved in a liquid-liquid, two-phase system under ambient conditions. Nitric acid offers a dual function of an oxidant as well as a proton donor, which is essential for oxidative bromination using metal bromide salts. Bromination as well as chlorination could be accomplished with this simple system.",

author = "Joshi, \{Ashutosh V.\} and Mubeen Baidossi and Sudip Mukhopadhyay and Yoel Sasson",

year = "2004",

month = jul,

doi = "10.1021/op030055w",

language = "אנגלית",

volume = "8",

pages = "568--570",

journal = "Organic Process Research and Development",

issn = "1083-6160",

publisher = "American Chemical Society",

number = "4",

}

TY - JOUR

T1 - OOxidative bromination of activated aromatic compounds using aqueous nitric acid as an oxidant

AU - Joshi, Ashutosh V.

AU - Baidossi, Mubeen

AU - Mukhopadhyay, Sudip

AU - Sasson, Yoel

PY - 2004/7

Y1 - 2004/7

N2 - Oxidative bromination of activated aromatic compounds using alkali metal bromide salts and aqueous nitric acid to the corresponding bromo-derivatives is achieved in a liquid-liquid, two-phase system under ambient conditions. Nitric acid offers a dual function of an oxidant as well as a proton donor, which is essential for oxidative bromination using metal bromide salts. Bromination as well as chlorination could be accomplished with this simple system.

AB - Oxidative bromination of activated aromatic compounds using alkali metal bromide salts and aqueous nitric acid to the corresponding bromo-derivatives is achieved in a liquid-liquid, two-phase system under ambient conditions. Nitric acid offers a dual function of an oxidant as well as a proton donor, which is essential for oxidative bromination using metal bromide salts. Bromination as well as chlorination could be accomplished with this simple system.

UR - https://www.scopus.com/pages/publications/4243059492

U2 - 10.1021/op030055w

DO - 10.1021/op030055w

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:4243059492

SN - 1083-6160

VL - 8

SP - 568

EP - 570

JO - Organic Process Research and Development

JF - Organic Process Research and Development

IS - 4

ER -

OOxidative bromination of activated aromatic compounds using aqueous nitric acid as an oxidant

Abstract

Access to Document

Other files and links

Fingerprint

Cite this