OOxidative bromination of activated aromatic compounds using aqueous nitric acid as an oxidant

Ashutosh V. Joshi; Mubeen Baidossi; Sudip Mukhopadhyay; Yoel Sasson

doi:10.1021/op030055w

OOxidative bromination of activated aromatic compounds using aqueous nitric acid as an oxidant

Ashutosh V. Joshi
, Mubeen Baidossi
, Sudip Mukhopadhyay^*
, Yoel Sasson

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Oxidative bromination of activated aromatic compounds using alkali metal bromide salts and aqueous nitric acid to the corresponding bromo-derivatives is achieved in a liquid-liquid, two-phase system under ambient conditions. Nitric acid offers a dual function of an oxidant as well as a proton donor, which is essential for oxidative bromination using metal bromide salts. Bromination as well as chlorination could be accomplished with this simple system.

Original language	English
Pages (from-to)	568-570
Number of pages	3
Journal	Organic Process Research and Development
Volume	8
Issue number	4
DOIs	https://doi.org/10.1021/op030055w
State	Published - Jul 2004

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title = "OOxidative bromination of activated aromatic compounds using aqueous nitric acid as an oxidant",

abstract = "Oxidative bromination of activated aromatic compounds using alkali metal bromide salts and aqueous nitric acid to the corresponding bromo-derivatives is achieved in a liquid-liquid, two-phase system under ambient conditions. Nitric acid offers a dual function of an oxidant as well as a proton donor, which is essential for oxidative bromination using metal bromide salts. Bromination as well as chlorination could be accomplished with this simple system.",

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AU - Joshi, Ashutosh V.

AU - Baidossi, Mubeen

AU - Mukhopadhyay, Sudip

AU - Sasson, Yoel

PY - 2004/7

Y1 - 2004/7

N2 - Oxidative bromination of activated aromatic compounds using alkali metal bromide salts and aqueous nitric acid to the corresponding bromo-derivatives is achieved in a liquid-liquid, two-phase system under ambient conditions. Nitric acid offers a dual function of an oxidant as well as a proton donor, which is essential for oxidative bromination using metal bromide salts. Bromination as well as chlorination could be accomplished with this simple system.

AB - Oxidative bromination of activated aromatic compounds using alkali metal bromide salts and aqueous nitric acid to the corresponding bromo-derivatives is achieved in a liquid-liquid, two-phase system under ambient conditions. Nitric acid offers a dual function of an oxidant as well as a proton donor, which is essential for oxidative bromination using metal bromide salts. Bromination as well as chlorination could be accomplished with this simple system.

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ER -

OOxidative bromination of activated aromatic compounds using aqueous nitric acid as an oxidant

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