TY - JOUR
T1 - Organic Reactions in Melts and Solids. Part III
T2 - Hydrogenolysis by Neat Acyloins
AU - Goldberg, O.
AU - Michman, M.
AU - Patai, S.
PY - 1965
Y1 - 1965
N2 - Acyloins were investigated as hydrogen donors in thermal reactions. With neat materials, satisfactory yields were obtained when weak oxidants such as mercuric cyanide and other mercuric salts were used as hydrogen acceptors. The reactions show a high degree of selectivity: acyloins alone are oxidized by mercuric cyanide while compounds of related structure do not react. The reactions of neat materials, in the molten state, yield results which clearly differ from those previously obtained in various solvents.
AB - Acyloins were investigated as hydrogen donors in thermal reactions. With neat materials, satisfactory yields were obtained when weak oxidants such as mercuric cyanide and other mercuric salts were used as hydrogen acceptors. The reactions show a high degree of selectivity: acyloins alone are oxidized by mercuric cyanide while compounds of related structure do not react. The reactions of neat materials, in the molten state, yield results which clearly differ from those previously obtained in various solvents.
UR - http://www.scopus.com/inward/record.url?scp=84989996241&partnerID=8YFLogxK
U2 - 10.1002/ijch.196500054
DO - 10.1002/ijch.196500054
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AN - SCOPUS:84989996241
SN - 0021-2148
VL - 3
SP - 229
EP - 233
JO - Israel Journal of Chemistry
JF - Israel Journal of Chemistry
IS - 6
ER -