TY - JOUR
T1 - Organic reactions in melts and solids. Part IX. Thermogravimetric studies of reactions between acetanilide and aromatic monocarboxylic acids
AU - Michman, Michael
AU - Meidar, David
PY - 1972
Y1 - 1972
N2 - Isothermal thermogravimetric analysis was used to follow the transacylation reactions in melts of acetanilide with 3,5-dinitrobenzoic acid, 1-naphthoic acid, and 4-methoxybenzoic acid. Reactions were carried out at 106 and 110° with anhydrous aluminium chloride as catalyst. They were found to be of the second order (first order in acetanilide and in the acid). The correlations of rate coefficients with acid strengths and with the concentrations of reactants and catalyst were studied.
AB - Isothermal thermogravimetric analysis was used to follow the transacylation reactions in melts of acetanilide with 3,5-dinitrobenzoic acid, 1-naphthoic acid, and 4-methoxybenzoic acid. Reactions were carried out at 106 and 110° with anhydrous aluminium chloride as catalyst. They were found to be of the second order (first order in acetanilide and in the acid). The correlations of rate coefficients with acid strengths and with the concentrations of reactants and catalyst were studied.
UR - http://www.scopus.com/inward/record.url?scp=37049120708&partnerID=8YFLogxK
U2 - 10.1039/p29720000300
DO - 10.1039/p29720000300
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AN - SCOPUS:37049120708
SN - 1472-779X
SP - 300
EP - 304
JO - Journal of the Chemical Society, Perkin Transactions 2
JF - Journal of the Chemical Society, Perkin Transactions 2
IS - 3
ER -