Orientation dependence of the induction contribution in molecule-graphite interactions

David B. Whitehouse; A. David Buckingham; Richard B. Bernstein; Victoria A. Cho; Raphael D. Levine

doi:10.1021/j100174a029

Orientation dependence of the induction contribution in molecule-graphite interactions

David B. Whitehouse
, A. David Buckingham^*
, Richard B. Bernstein
, Victoria A. Cho
, Raphael D. Levine

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

A simple electrostatic model is used to evaluate the orientation dependence of the induction contribution to the molecule-graphite potential for 13 polar molecules. The results are employed to help rationalize the experimental observation of orientation-dependent trapping probabilities of molecules scattered from a graphite(0001) surface. The approach is successful in predicting the correct sign of the steric effect for the majority of molecules under investigation.

Original language	English
Pages (from-to)	8175-8177
Number of pages	3
Journal	Journal of Physical Chemistry
Volume	95
Issue number	21
DOIs	https://doi.org/10.1021/j100174a029
State	Published - 1991
Externally published	Yes

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10.1021/j100174a029

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title = "Orientation dependence of the induction contribution in molecule-graphite interactions",

abstract = "A simple electrostatic model is used to evaluate the orientation dependence of the induction contribution to the molecule-graphite potential for 13 polar molecules. The results are employed to help rationalize the experimental observation of orientation-dependent trapping probabilities of molecules scattered from a graphite(0001) surface. The approach is successful in predicting the correct sign of the steric effect for the majority of molecules under investigation.",

author = "Whitehouse, \{David B.\} and Buckingham, \{A. David\} and Bernstein, \{Richard B.\} and Cho, \{Victoria A.\} and Levine, \{Raphael D.\}",

year = "1991",

doi = "10.1021/j100174a029",

language = "אנגלית",

volume = "95",

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journal = "Journal of Physical Chemistry",

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T1 - Orientation dependence of the induction contribution in molecule-graphite interactions

AU - Whitehouse, David B.

AU - Buckingham, A. David

AU - Bernstein, Richard B.

AU - Cho, Victoria A.

AU - Levine, Raphael D.

PY - 1991

Y1 - 1991

N2 - A simple electrostatic model is used to evaluate the orientation dependence of the induction contribution to the molecule-graphite potential for 13 polar molecules. The results are employed to help rationalize the experimental observation of orientation-dependent trapping probabilities of molecules scattered from a graphite(0001) surface. The approach is successful in predicting the correct sign of the steric effect for the majority of molecules under investigation.

AB - A simple electrostatic model is used to evaluate the orientation dependence of the induction contribution to the molecule-graphite potential for 13 polar molecules. The results are employed to help rationalize the experimental observation of orientation-dependent trapping probabilities of molecules scattered from a graphite(0001) surface. The approach is successful in predicting the correct sign of the steric effect for the majority of molecules under investigation.

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DO - 10.1021/j100174a029

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AN - SCOPUS:33751499659

SN - 0022-3654

VL - 95

SP - 8175

EP - 8177

JO - Journal of Physical Chemistry

JF - Journal of Physical Chemistry

IS - 21

ER -

Orientation dependence of the induction contribution in molecule-graphite interactions

Abstract

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