Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion

Manfred Lissel; Helmut Jansen in de Wal; Ronny Neumann

doi:10.1016/S0040-4039(00)91735-0

Oxidation of activated phenols by dioxygen catalysed by the H₅PV₂Mo₁₀O₄₀ heteropolyanion

Manfred Lissel^*, Helmut Jansen in de Wal, Ronny Neumann

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

86 Scopus citations

Abstract

The H₅PV₂Mo₁₀O₄₀ heteropolyanion has been found to catalyse the highly selective aerobic oxidation of dialkylphenols to diphenoquinones and the oxidation of 2, 3, 5-trimethylphenol to the 2, 3, 5-trimethyl-1, 4-benzoquinone. The rate is highly dependent on the oxidation potential of the substrate and is proceeds by electron transfer from the phenol substrate to the heteropolyanion catalyst.

Original language	English
Pages (from-to)	1795-1798
Number of pages	4
Journal	Tetrahedron Letters
Volume	33
Issue number	13
DOIs	https://doi.org/10.1016/S0040-4039(00)91735-0
State	Published - 24 Mar 1992

Keywords

Dioxygen
Heteropolyanions
Phenol Oxidation

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title = "Oxidation of activated phenols by dioxygen catalysed by the H5PV2Mo10O40 heteropolyanion",

abstract = "The H5PV2Mo10O40 heteropolyanion has been found to catalyse the highly selective aerobic oxidation of dialkylphenols to diphenoquinones and the oxidation of 2, 3, 5-trimethylphenol to the 2, 3, 5-trimethyl-1, 4-benzoquinone. The rate is highly dependent on the oxidation potential of the substrate and is proceeds by electron transfer from the phenol substrate to the heteropolyanion catalyst.",

keywords = "Dioxygen, Heteropolyanions, Phenol Oxidation",

author = "Manfred Lissel and {in de Wal}, {Helmut Jansen} and Ronny Neumann",

year = "1992",

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doi = "10.1016/S0040-4039(00)91735-0",

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AU - Lissel, Manfred

AU - in de Wal, Helmut Jansen

AU - Neumann, Ronny

PY - 1992/3/24

Y1 - 1992/3/24

N2 - The H5PV2Mo10O40 heteropolyanion has been found to catalyse the highly selective aerobic oxidation of dialkylphenols to diphenoquinones and the oxidation of 2, 3, 5-trimethylphenol to the 2, 3, 5-trimethyl-1, 4-benzoquinone. The rate is highly dependent on the oxidation potential of the substrate and is proceeds by electron transfer from the phenol substrate to the heteropolyanion catalyst.

AB - The H5PV2Mo10O40 heteropolyanion has been found to catalyse the highly selective aerobic oxidation of dialkylphenols to diphenoquinones and the oxidation of 2, 3, 5-trimethylphenol to the 2, 3, 5-trimethyl-1, 4-benzoquinone. The rate is highly dependent on the oxidation potential of the substrate and is proceeds by electron transfer from the phenol substrate to the heteropolyanion catalyst.

KW - Dioxygen

KW - Heteropolyanions

KW - Phenol Oxidation

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JO - Tetrahedron Letters

JF - Tetrahedron Letters

IS - 13

ER -

Oxidation of activated phenols by dioxygen catalysed by the H₅PV₂Mo₁₀O₄₀ heteropolyanion

Abstract

Keywords

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