Oxidations with hydrogen peroxide catalysed by the [WZnMn(II)2(ZnW9O34)2] 12-polyoxometalate

Ronny Neumann; David Juwiler

doi:10.1016/0040-4020(96)00419-X

Oxidations with hydrogen peroxide catalysed by the [WZnMn(II)₂(ZnW₉O₃₄)₂] ¹²-polyoxometalate

Ronny Neumann^*
, David Juwiler

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

Polyoxometalates can be used as catalysts for the activation of molecular oxygen and 30% aqueous hydrogen peroxide for the selective transformation of various organic substrates. In this paper results are presented for the oxidation of alkenes, dienes, alkenols, and sulfides using 30% aqueous H₂O₂ as oxidant and [WZnMn(II)₂(ZnW₉O₃₄)₂] ¹²-as catalyst. In certain but not all cases high reactivity, chemoselectivity and sterospecificity has been observed especially in the epoxidation of alkenols with primary hydroxyl units.

Original language	English
Pages (from-to)	8781-8788
Number of pages	8
Journal	Tetrahedron
Volume	52
Issue number	26
DOIs	https://doi.org/10.1016/0040-4020(96)00419-X
State	Published - Jun 1996

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abstract = "Polyoxometalates can be used as catalysts for the activation of molecular oxygen and 30\% aqueous hydrogen peroxide for the selective transformation of various organic substrates. In this paper results are presented for the oxidation of alkenes, dienes, alkenols, and sulfides using 30\% aqueous H2O2 as oxidant and [WZnMn(II)2(ZnW9O34)2] 12-as catalyst. In certain but not all cases high reactivity, chemoselectivity and sterospecificity has been observed especially in the epoxidation of alkenols with primary hydroxyl units.",

author = "Ronny Neumann and David Juwiler",

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AB - Polyoxometalates can be used as catalysts for the activation of molecular oxygen and 30% aqueous hydrogen peroxide for the selective transformation of various organic substrates. In this paper results are presented for the oxidation of alkenes, dienes, alkenols, and sulfides using 30% aqueous H2O2 as oxidant and [WZnMn(II)2(ZnW9O34)2] 12-as catalyst. In certain but not all cases high reactivity, chemoselectivity and sterospecificity has been observed especially in the epoxidation of alkenols with primary hydroxyl units.

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Oxidations with hydrogen peroxide catalysed by the [WZnMn(II)₂(ZnW₉O₃₄)₂] ¹²-polyoxometalate

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