Palladium-catalyzed decomposition of aqueous alkali metal formate solutions

Harold Wiener; Yoel Sasson; Jochanan Blum

doi:10.1016/0304-5102(86)87075-4

Palladium-catalyzed decomposition of aqueous alkali metal formate solutions

Harold Wiener^*, Yoel Sasson, Jochanan Blum

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

83 Scopus citations

Abstract

Aqueous sodium and potassium formate solutions undergo catalytic decomposition, under mild conditions, into molecular hydrogen and hydrogen carbonate in the presence of palladium on carbon. Both the formate and water hydrogen atoms are involved in the process and undergo fast exchange. Some kinetic and mechanistic features of the decomposition reaction are reported.

Original language	English
Pages (from-to)	277-284
Number of pages	8
Journal	Journal of Molecular Catalysis
Volume	35
Issue number	3
DOIs	https://doi.org/10.1016/0304-5102(86)87075-4
State	Published - Jun 1986

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title = "Palladium-catalyzed decomposition of aqueous alkali metal formate solutions",

abstract = "Aqueous sodium and potassium formate solutions undergo catalytic decomposition, under mild conditions, into molecular hydrogen and hydrogen carbonate in the presence of palladium on carbon. Both the formate and water hydrogen atoms are involved in the process and undergo fast exchange. Some kinetic and mechanistic features of the decomposition reaction are reported.",

author = "Harold Wiener and Yoel Sasson and Jochanan Blum",

year = "1986",

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T1 - Palladium-catalyzed decomposition of aqueous alkali metal formate solutions

AU - Wiener, Harold

AU - Sasson, Yoel

AU - Blum, Jochanan

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N2 - Aqueous sodium and potassium formate solutions undergo catalytic decomposition, under mild conditions, into molecular hydrogen and hydrogen carbonate in the presence of palladium on carbon. Both the formate and water hydrogen atoms are involved in the process and undergo fast exchange. Some kinetic and mechanistic features of the decomposition reaction are reported.

AB - Aqueous sodium and potassium formate solutions undergo catalytic decomposition, under mild conditions, into molecular hydrogen and hydrogen carbonate in the presence of palladium on carbon. Both the formate and water hydrogen atoms are involved in the process and undergo fast exchange. Some kinetic and mechanistic features of the decomposition reaction are reported.

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JO - Journal of Molecular Catalysis

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IS - 3

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Palladium-catalyzed decomposition of aqueous alkali metal formate solutions

Abstract

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