Peripheral chemical reactions

M. Ben-Nun; M. Brouard; J. P. Simons; R. D. Levine

doi:10.1016/0009-2614(93)87048-8

Peripheral chemical reactions

M. Ben-Nun^*, M. Brouard, J. P. Simons, R. D. Levine

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

38 Scopus citations

Abstract

Forward scattering of the products of direct exoergic atom transfer reactions is proposed as an indication for a peripheral attraction: a reaction in which an atom at the periphery of the reactants is abstracted. Model computations for the O(¹D) + N₂O reaction are used to illustrate the proposed mechanism. The opacity function has a peak at higher impact parameters which is correlated with the forward scattering. Potential energy surfaces which do not manifest peripheral attraction lead to backwards scattering of the products.

Original language	English
Pages (from-to)	423-431
Number of pages	9
Journal	Chemical Physics Letters
Volume	210
Issue number	4-6
DOIs	https://doi.org/10.1016/0009-2614(93)87048-8
State	Published - 30 Jul 1993

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title = "Peripheral chemical reactions",

abstract = "Forward scattering of the products of direct exoergic atom transfer reactions is proposed as an indication for a peripheral attraction: a reaction in which an atom at the periphery of the reactants is abstracted. Model computations for the O(1D) + N2O reaction are used to illustrate the proposed mechanism. The opacity function has a peak at higher impact parameters which is correlated with the forward scattering. Potential energy surfaces which do not manifest peripheral attraction lead to backwards scattering of the products.",

author = "M. Ben-Nun and M. Brouard and Simons, \{J. P.\} and Levine, \{R. D.\}",

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AU - Ben-Nun, M.

AU - Brouard, M.

AU - Simons, J. P.

AU - Levine, R. D.

PY - 1993/7/30

Y1 - 1993/7/30

N2 - Forward scattering of the products of direct exoergic atom transfer reactions is proposed as an indication for a peripheral attraction: a reaction in which an atom at the periphery of the reactants is abstracted. Model computations for the O(1D) + N2O reaction are used to illustrate the proposed mechanism. The opacity function has a peak at higher impact parameters which is correlated with the forward scattering. Potential energy surfaces which do not manifest peripheral attraction lead to backwards scattering of the products.

AB - Forward scattering of the products of direct exoergic atom transfer reactions is proposed as an indication for a peripheral attraction: a reaction in which an atom at the periphery of the reactants is abstracted. Model computations for the O(1D) + N2O reaction are used to illustrate the proposed mechanism. The opacity function has a peak at higher impact parameters which is correlated with the forward scattering. Potential energy surfaces which do not manifest peripheral attraction lead to backwards scattering of the products.

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JO - Chemical Physics Letters

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Peripheral chemical reactions

Abstract

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