Abstract
The mechanism by which microcapsule aggregation is diminished in the presence of low concentrations of adjunct non-walling polymers such as polyisobutylene PIB in organic solvents is uncertain. It is here investigated by phase separation studies employing the non-solvent addition method cyclohexane in parallel with microencapsulation experiments, using Eudragit wall polymers and tetrahy-drofurane THF as solvent with and without PIB. Polymer incompatibility leads to formation of two dilute liquid phases and emulsification from the outset. Progressive solvent transfer to the PIB phase modulates the rate of wall polymer desolvation and maintains the concentrated wall polymer phase in a fluid state during the critical microencapsulation stages of wall polymer entrapmen and spreading. A three-phase system is formed when gelling ensues L1+ L2 + gel In the absence of PIB, phase separation leads immediately to deposition of the wall polymer in gel form L1+ gel leading to adhesion. Phase diagrams are presented.
Original language | American English |
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Pages (from-to) | 1-15 |
Number of pages | 15 |
Journal | Journal of Microencapsulation |
Volume | 7 |
Issue number | 1 |
DOIs | |
State | Published - 1990 |