TY - JOUR
T1 - Phase Transfer Catalyzed Bromide—Chloride Exchange
T2 - Dependence of Equilibrium Position and Selectivity Constant on Nature and Composition of Aqueous Phase
AU - Yonovich‐Weiss, Minda
AU - Sasson, Yoel
PY - 1985
Y1 - 1985
N2 - The position of the equilibrium in the PTC exchange reaction of alkyl chloride with metal bromide salts RCl + MBr ⇌ RBr + MCI under various condtions is utilized for calculation of the selectivity constant KselCl/Br. This constant is found to be dependent on the nature of the metal cation and the inorganic phase composition. KselCl/Br can be defined for any point on the phase diagram MCl—MBr—H2O at a given temperature, solvent and quaternary cation.
AB - The position of the equilibrium in the PTC exchange reaction of alkyl chloride with metal bromide salts RCl + MBr ⇌ RBr + MCI under various condtions is utilized for calculation of the selectivity constant KselCl/Br. This constant is found to be dependent on the nature of the metal cation and the inorganic phase composition. KselCl/Br can be defined for any point on the phase diagram MCl—MBr—H2O at a given temperature, solvent and quaternary cation.
UR - http://www.scopus.com/inward/record.url?scp=84985080236&partnerID=8YFLogxK
U2 - 10.1002/ijch.198500103
DO - 10.1002/ijch.198500103
M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???
AN - SCOPUS:84985080236
SN - 0021-2148
VL - 26
SP - 243
EP - 247
JO - Israel Journal of Chemistry
JF - Israel Journal of Chemistry
IS - 3
ER -