TY - JOUR
T1 - Photocatalysed regeneration of NAD(P)H by CdS and TiO2 semiconductors
T2 - applications in enzymatic synthesis
AU - Goren, Zafrir
AU - Lapidot, Noa
AU - Willner, Itamar
PY - 1988/8/15
Y1 - 1988/8/15
N2 - Photocatalysed regeneration of NAD(P)H is accomplished with CdS semiconductor powder and TiO2 colloids using formate or mercaptoethanol as electron donors. In these systems, methyl viologen acts as a primary charge relay for conduction band electrons. The reduced photoproduct, MV+., mediates the regeneration of NAD(P)H in the presence of enzymes. The NADH regeneration cycles have been coupled to the synthesis of alanine, malic acid and lactic acid.
AB - Photocatalysed regeneration of NAD(P)H is accomplished with CdS semiconductor powder and TiO2 colloids using formate or mercaptoethanol as electron donors. In these systems, methyl viologen acts as a primary charge relay for conduction band electrons. The reduced photoproduct, MV+., mediates the regeneration of NAD(P)H in the presence of enzymes. The NADH regeneration cycles have been coupled to the synthesis of alanine, malic acid and lactic acid.
UR - http://www.scopus.com/inward/record.url?scp=0024057676&partnerID=8YFLogxK
U2 - 10.1016/0304-5102(88)85069-7
DO - 10.1016/0304-5102(88)85069-7
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AN - SCOPUS:0024057676
SN - 0304-5102
VL - 47
SP - 21
EP - 32
JO - Journal of Molecular Catalysis
JF - Journal of Molecular Catalysis
IS - 1
ER -