TY - JOUR
T1 - Photochemical asymmetric synthesis irradiation of mannitol hexacinnamate
AU - Green, Bernard S.
AU - Rabinsohn, Yechiel
AU - Rejto, Miriam
PY - 1975
Y1 - 1975
N2 - Intramolecular photocycloaddition takes place when a solution of mannitol hexacinnamate is irradiated (λ > 290 nm) and, after ester exchange with excess of methanol and chromatographic separation, methyl cinnamate, dimethyl β-truxinate, (±)-dimethyl neo-truxi-nate, and (+)-dimethyl δ-truxinate are isolated; the optical yield of the latter is as high as 46%.
AB - Intramolecular photocycloaddition takes place when a solution of mannitol hexacinnamate is irradiated (λ > 290 nm) and, after ester exchange with excess of methanol and chromatographic separation, methyl cinnamate, dimethyl β-truxinate, (±)-dimethyl neo-truxi-nate, and (+)-dimethyl δ-truxinate are isolated; the optical yield of the latter is as high as 46%.
UR - http://www.scopus.com/inward/record.url?scp=0010509097&partnerID=8YFLogxK
U2 - 10.1039/C39750000313
DO - 10.1039/C39750000313
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AN - SCOPUS:0010509097
SN - 0022-4936
SP - 313
EP - 314
JO - Chemical Communications
JF - Chemical Communications
IS - 9
ER -