Photochemistry of caged molecules: CD3Cl@ice

Y. Lilach; M. Asscher

doi:10.1063/1.1577534

Photochemistry of caged molecules: CD₃Cl@ice

Y. Lilach, M. Asscher^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

22 Scopus citations

Abstract

Photoinitiated reactions that take place within cages of methyl chloride molecules inside ASW-CD₃Cl@Ice was studied in molecular level mechanistic details. It was found that cage walls made of ASW substantially suppress the overall DEA process and thus the photoreactivity that results from it. At a photon energy of 5.0 eV, the cross sections are about an order of magnitude smaller than these at 6.4 eV.

Original language	English
Pages (from-to)	407-412
Number of pages	6
Journal	Journal of Chemical Physics
Volume	119
Issue number	1
DOIs	https://doi.org/10.1063/1.1577534
State	Published - 1 Jul 2003

Access to Document

10.1063/1.1577534

Cite this

@article{40d772180e4243cd926bc7d28101fbe1,

title = "Photochemistry of caged molecules: CD3Cl@ice",

abstract = "Photoinitiated reactions that take place within cages of methyl chloride molecules inside ASW-CD3Cl@Ice was studied in molecular level mechanistic details. It was found that cage walls made of ASW substantially suppress the overall DEA process and thus the photoreactivity that results from it. At a photon energy of 5.0 eV, the cross sections are about an order of magnitude smaller than these at 6.4 eV.",

author = "Y. Lilach and M. Asscher",

year = "2003",

month = jul,

day = "1",

doi = "10.1063/1.1577534",

language = "אנגלית",

volume = "119",

pages = "407--412",

journal = "Journal of Chemical Physics",

issn = "0021-9606",

publisher = "American Institute of Physics",

number = "1",

}

TY - JOUR

T1 - Photochemistry of caged molecules

T2 - CD3Cl@ice

AU - Lilach, Y.

AU - Asscher, M.

PY - 2003/7/1

Y1 - 2003/7/1

N2 - Photoinitiated reactions that take place within cages of methyl chloride molecules inside ASW-CD3Cl@Ice was studied in molecular level mechanistic details. It was found that cage walls made of ASW substantially suppress the overall DEA process and thus the photoreactivity that results from it. At a photon energy of 5.0 eV, the cross sections are about an order of magnitude smaller than these at 6.4 eV.

AB - Photoinitiated reactions that take place within cages of methyl chloride molecules inside ASW-CD3Cl@Ice was studied in molecular level mechanistic details. It was found that cage walls made of ASW substantially suppress the overall DEA process and thus the photoreactivity that results from it. At a photon energy of 5.0 eV, the cross sections are about an order of magnitude smaller than these at 6.4 eV.

UR - http://www.scopus.com/inward/record.url?scp=0038107509&partnerID=8YFLogxK

U2 - 10.1063/1.1577534

DO - 10.1063/1.1577534

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0038107509

SN - 0021-9606

VL - 119

SP - 407

EP - 412

JO - Journal of Chemical Physics

JF - Journal of Chemical Physics

IS - 1

ER -

Photochemistry of caged molecules: CD₃Cl@ice

Abstract

Access to Document

Other files and links

Fingerprint

Cite this