Photodimerization and Excimer Emission in a Crystalline 1,4-Diphenylbutadiene

M. D. Cohen; A. Elgavi; B. S. Green; Z. Ludmer; G. M.J. Schmidt

doi:10.1021/ja00774a034

Photodimerization and Excimer Emission in a Crystalline 1,4-Diphenylbutadiene

M. D. Cohen^*, A. Elgavi, B. S. Green, Z. Ludmer, G. M.J. Schmidt

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

42 Scopus citations

Abstract

Crystalline 1-(2,6-dichlorophenyl)-4-phenyl-trans,trans-buta-1,3-diene (5) displays excimer emission while the crystalline nonchloro analog (2) and solutions of both compounds exhibit only monomer emission. Solid 5, unlike 2, undergoes reaction on irradiation yielding only one of two topochemically-allowed, mirror-symmetric photodimers.

Original language	English
Pages (from-to)	6776-6779
Number of pages	4
Journal	Journal of the American Chemical Society
Volume	94
Issue number	19
DOIs	https://doi.org/10.1021/ja00774a034
State	Published - 1 Sep 1972
Externally published	Yes

Access to Document

10.1021/ja00774a034

Cite this

@article{36c898f0a64b4b7f9e59ac74e665fdf9,

title = "Photodimerization and Excimer Emission in a Crystalline 1,4-Diphenylbutadiene",

abstract = "Crystalline 1-(2,6-dichlorophenyl)-4-phenyl-trans,trans-buta-1,3-diene (5) displays excimer emission while the crystalline nonchloro analog (2) and solutions of both compounds exhibit only monomer emission. Solid 5, unlike 2, undergoes reaction on irradiation yielding only one of two topochemically-allowed, mirror-symmetric photodimers.",

author = "Cohen, {M. D.} and A. Elgavi and Green, {B. S.} and Z. Ludmer and Schmidt, {G. M.J.}",

year = "1972",

month = sep,

day = "1",

doi = "10.1021/ja00774a034",

language = "אנגלית",

volume = "94",

pages = "6776--6779",

journal = "Journal of the American Chemical Society",

issn = "0002-7863",

publisher = "American Chemical Society",

number = "19",

}

TY - JOUR

T1 - Photodimerization and Excimer Emission in a Crystalline 1,4-Diphenylbutadiene

AU - Cohen, M. D.

AU - Elgavi, A.

AU - Green, B. S.

AU - Ludmer, Z.

AU - Schmidt, G. M.J.

PY - 1972/9/1

Y1 - 1972/9/1

N2 - Crystalline 1-(2,6-dichlorophenyl)-4-phenyl-trans,trans-buta-1,3-diene (5) displays excimer emission while the crystalline nonchloro analog (2) and solutions of both compounds exhibit only monomer emission. Solid 5, unlike 2, undergoes reaction on irradiation yielding only one of two topochemically-allowed, mirror-symmetric photodimers.

AB - Crystalline 1-(2,6-dichlorophenyl)-4-phenyl-trans,trans-buta-1,3-diene (5) displays excimer emission while the crystalline nonchloro analog (2) and solutions of both compounds exhibit only monomer emission. Solid 5, unlike 2, undergoes reaction on irradiation yielding only one of two topochemically-allowed, mirror-symmetric photodimers.

UR - http://www.scopus.com/inward/record.url?scp=0001360856&partnerID=8YFLogxK

U2 - 10.1021/ja00774a034

DO - 10.1021/ja00774a034

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0001360856

SN - 0002-7863

VL - 94

SP - 6776

EP - 6779

JO - Journal of the American Chemical Society

JF - Journal of the American Chemical Society

IS - 19

ER -

Photodimerization and Excimer Emission in a Crystalline 1,4-Diphenylbutadiene

Abstract

Access to Document

Other files and links

Fingerprint

Cite this