TY - JOUR
T1 - Photodissociation of ICN in solid and in liquid Ar
T2 - Dynamics of the cage effect and of excited-state isomerization
AU - Krylov, A. I.
AU - Gerber, R. B.
PY - 1994
Y1 - 1994
N2 - Photodissociation of ICN by UV excitation in solid and liquid Ar is studied by molecular dynamics simulations. The focus is on the differences between the cage effects on the CN photoproduct in the two phases, and on the excited state isomerization ICN*→INC* dynamics in the solid matrix. Nonadiabatic transitions are neglected in this first study. The main results are: (1) No cage exit of the CN product is found in solid Ar, even in simulations at temperatures close to melting and for large excess energies. The result is in accord with recent experiments by Fraenkel and Haas. This should be contrasted with the large cage-exit probabilities found in many systems for atomic photofragments. The result is interpreted in terms of geometric and energy transfer considerations. It is predicted that complete caging of diatomic and larger photofragments will be typically the case for photodissociation in rare-gas matrices. (2) Almost 100% cage-exit probability for the CN product is found for ICN photolysis on the 1Π1 potential surface in liquid Ar. On the other hand, photolysis on 3Π0+ potential surface does not lead to cage exit on a time scale of 15 ps. The large differences between the reaction in the solid and in the liquid, and between the behavior of the process on the 3Π0+ and the 1Π1 potentials, respectively in the liquid, are interpreted. (3) CN rotational dynamics and subsequent relaxation leads to isomerization in the excited electronic states. On the 3Π 0+ potential surface one finds after t≳0.5 ps roughly equal amounts of the ICN and INC isomers. On the 1Π1 surfaces only INC is found after t≳3.5 ps. This is explained in terms of the barriers for CN rotation in the two excited states, and in terms of the time scales for rotational relaxation. The results throw light on the differences between cage effects for photochemical reactions in solid and in liquid solution, and on cage-induced isomerization dynamics in solid matrices.
AB - Photodissociation of ICN by UV excitation in solid and liquid Ar is studied by molecular dynamics simulations. The focus is on the differences between the cage effects on the CN photoproduct in the two phases, and on the excited state isomerization ICN*→INC* dynamics in the solid matrix. Nonadiabatic transitions are neglected in this first study. The main results are: (1) No cage exit of the CN product is found in solid Ar, even in simulations at temperatures close to melting and for large excess energies. The result is in accord with recent experiments by Fraenkel and Haas. This should be contrasted with the large cage-exit probabilities found in many systems for atomic photofragments. The result is interpreted in terms of geometric and energy transfer considerations. It is predicted that complete caging of diatomic and larger photofragments will be typically the case for photodissociation in rare-gas matrices. (2) Almost 100% cage-exit probability for the CN product is found for ICN photolysis on the 1Π1 potential surface in liquid Ar. On the other hand, photolysis on 3Π0+ potential surface does not lead to cage exit on a time scale of 15 ps. The large differences between the reaction in the solid and in the liquid, and between the behavior of the process on the 3Π0+ and the 1Π1 potentials, respectively in the liquid, are interpreted. (3) CN rotational dynamics and subsequent relaxation leads to isomerization in the excited electronic states. On the 3Π 0+ potential surface one finds after t≳0.5 ps roughly equal amounts of the ICN and INC isomers. On the 1Π1 surfaces only INC is found after t≳3.5 ps. This is explained in terms of the barriers for CN rotation in the two excited states, and in terms of the time scales for rotational relaxation. The results throw light on the differences between cage effects for photochemical reactions in solid and in liquid solution, and on cage-induced isomerization dynamics in solid matrices.
UR - http://www.scopus.com/inward/record.url?scp=36449004914&partnerID=8YFLogxK
U2 - 10.1063/1.466306
DO - 10.1063/1.466306
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AN - SCOPUS:36449004914
SN - 0021-9606
VL - 100
SP - 4242
EP - 4252
JO - The Journal of Chemical Physics
JF - The Journal of Chemical Physics
IS - 6
ER -