Polyethylated triptycene derivatives

Vered Marks; Moshe Nahmany; Hugo E. Gottlieb; Silvio E. Biali

doi:10.1021/jo026206v

Polyethylated triptycene derivatives

Vered Marks, Moshe Nahmany, Hugo E. Gottlieb^*, Silvio E. Biali

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

9 Scopus citations

Abstract

The octaethyl triptycenes 7 and 8 were synthesized by Diels - Alder reaction of the octaethylanthracene 4 with the corresponding benzynes. Low-temperature NMR spectra of 7 and 8 are consistent with the presence of the fully alternated conformation "a" of C₂ symmetry. However, in the determined crystal structures, the compounds adopt a higher energy conformation with a pair of vicinal ethyls oriented in the same direction.

Original language	English
Pages (from-to)	7898-7901
Number of pages	4
Journal	Journal of Organic Chemistry
Volume	67
Issue number	22
DOIs	https://doi.org/10.1021/jo026206v
State	Published - 1 Nov 2002

Access to Document

10.1021/jo026206v

Cite this

@article{274ec6068605463d8f04b68e20a67772,

title = "Polyethylated triptycene derivatives",

abstract = "The octaethyl triptycenes 7 and 8 were synthesized by Diels - Alder reaction of the octaethylanthracene 4 with the corresponding benzynes. Low-temperature NMR spectra of 7 and 8 are consistent with the presence of the fully alternated conformation {"}a{"} of C2 symmetry. However, in the determined crystal structures, the compounds adopt a higher energy conformation with a pair of vicinal ethyls oriented in the same direction.",

author = "Vered Marks and Moshe Nahmany and Gottlieb, {Hugo E.} and Biali, {Silvio E.}",

year = "2002",

month = nov,

day = "1",

doi = "10.1021/jo026206v",

language = "אנגלית",

volume = "67",

pages = "7898--7901",

journal = "Journal of Organic Chemistry",

issn = "0022-3263",

publisher = "American Chemical Society",

number = "22",

}

TY - JOUR

T1 - Polyethylated triptycene derivatives

AU - Marks, Vered

AU - Nahmany, Moshe

AU - Gottlieb, Hugo E.

AU - Biali, Silvio E.

PY - 2002/11/1

Y1 - 2002/11/1

N2 - The octaethyl triptycenes 7 and 8 were synthesized by Diels - Alder reaction of the octaethylanthracene 4 with the corresponding benzynes. Low-temperature NMR spectra of 7 and 8 are consistent with the presence of the fully alternated conformation "a" of C2 symmetry. However, in the determined crystal structures, the compounds adopt a higher energy conformation with a pair of vicinal ethyls oriented in the same direction.

AB - The octaethyl triptycenes 7 and 8 were synthesized by Diels - Alder reaction of the octaethylanthracene 4 with the corresponding benzynes. Low-temperature NMR spectra of 7 and 8 are consistent with the presence of the fully alternated conformation "a" of C2 symmetry. However, in the determined crystal structures, the compounds adopt a higher energy conformation with a pair of vicinal ethyls oriented in the same direction.

UR - http://www.scopus.com/inward/record.url?scp=0036827913&partnerID=8YFLogxK

U2 - 10.1021/jo026206v

DO - 10.1021/jo026206v

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0036827913

SN - 0022-3263

VL - 67

SP - 7898

EP - 7901

JO - Journal of Organic Chemistry

JF - Journal of Organic Chemistry

IS - 22

ER -

Polyethylated triptycene derivatives

Abstract

Access to Document

Other files and links

Fingerprint

Cite this