Abstract
Excellent deoxygenation of ketones and aldehydes is achieved with Keggin-type polyoxometalates in the presence of hydrogen (see Equation (1) for an example). The mixed addenda phosphovanadomolybdate [PV2Mo10O4]5- was found to be the best catalyst. X-ray diffraction and IR studies suggest that the polyoxometalates are structurally stable under the strongly reducing conditions.
Original language | English |
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Pages (from-to) | 3331-3334 |
Number of pages | 4 |
Journal | Angewandte Chemie - International Edition |
Volume | 38 |
Issue number | 22 |
DOIs | |
State | Published - 15 Nov 1999 |
Keywords
- Deoxygenations
- Heterogeneous catalysis hydrogenations
- Polyoxometalates
- Reductions