Polyoxometalates as reduction catalysts: Deoxygenation and hydrogenation of carbonyl compounds

Vladimir Kogan; Zeev Aizenshtat; Ronny Neumann

doi:10.1002/(SICI)1521-3773(19991115)38:22<3331::AID-ANIE3331>3.0.CO;2-Z

Polyoxometalates as reduction catalysts: Deoxygenation and hydrogenation of carbonyl compounds

Vladimir Kogan
, Zeev Aizenshtat
, Ronny Neumann^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

69 Scopus citations

Abstract

Excellent deoxygenation of ketones and aldehydes is achieved with Keggin-type polyoxometalates in the presence of hydrogen (see Equation (1) for an example). The mixed addenda phosphovanadomolybdate [PV₂Mo₁₀O₄]_5- was found to be the best catalyst. X-ray diffraction and IR studies suggest that the polyoxometalates are structurally stable under the strongly reducing conditions.

Original language	English
Pages (from-to)	3331-3334
Number of pages	4
Journal	Angewandte Chemie - International Edition
Volume	38
Issue number	22
DOIs	https://doi.org/10.1002/(SICI)1521-3773(19991115)38:22<3331::AID-ANIE3331>3.0.CO;2-Z
State	Published - 15 Nov 1999

Keywords

Deoxygenations
Heterogeneous catalysis hydrogenations
Polyoxometalates
Reductions

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10.1002/(SICI)1521-3773(19991115)38:22<3331::AID-ANIE3331>3.0.CO;2-Z

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title = "Polyoxometalates as reduction catalysts: Deoxygenation and hydrogenation of carbonyl compounds",

abstract = "Excellent deoxygenation of ketones and aldehydes is achieved with Keggin-type polyoxometalates in the presence of hydrogen (see Equation (1) for an example). The mixed addenda phosphovanadomolybdate [PV2Mo10O4]5- was found to be the best catalyst. X-ray diffraction and IR studies suggest that the polyoxometalates are structurally stable under the strongly reducing conditions.",

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T2 - Deoxygenation and hydrogenation of carbonyl compounds

AU - Kogan, Vladimir

AU - Aizenshtat, Zeev

AU - Neumann, Ronny

PY - 1999/11/15

Y1 - 1999/11/15

N2 - Excellent deoxygenation of ketones and aldehydes is achieved with Keggin-type polyoxometalates in the presence of hydrogen (see Equation (1) for an example). The mixed addenda phosphovanadomolybdate [PV2Mo10O4]5- was found to be the best catalyst. X-ray diffraction and IR studies suggest that the polyoxometalates are structurally stable under the strongly reducing conditions.

AB - Excellent deoxygenation of ketones and aldehydes is achieved with Keggin-type polyoxometalates in the presence of hydrogen (see Equation (1) for an example). The mixed addenda phosphovanadomolybdate [PV2Mo10O4]5- was found to be the best catalyst. X-ray diffraction and IR studies suggest that the polyoxometalates are structurally stable under the strongly reducing conditions.

KW - Deoxygenations

KW - Heterogeneous catalysis hydrogenations

KW - Polyoxometalates

KW - Reductions

UR - https://www.scopus.com/pages/publications/0033571642

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JO - Angewandte Chemie - International Edition

JF - Angewandte Chemie - International Edition

IS - 22

ER -

Polyoxometalates as reduction catalysts: Deoxygenation and hydrogenation of carbonyl compounds

Abstract

Keywords

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