Abstract
The preferential solvation parameters for the mutual association of acetonitrile with a co-solvent in their binary mixtures and for the self-association of acetonitrile in these mixtures, and the self-association of each of these components at infinite dilution in the other component as solvent have been determined. The co-solvents studied include dichloromethane, acetone and nitromethane that form practically ideal mixtures with acetonitrile and 1,2-dichloroethane and chloroform that nearly do so, as well as benzene, toluene, chlorobenzene, tetrarchloromethane, methanol, ethanol, acetic acid, formamide, dimethylformamide, and dimethylacetamide, which show appreciable preferential solvation.
| Original language | English |
|---|---|
| Pages (from-to) | 55-59 |
| Number of pages | 5 |
| Journal | Journal of Chemical Thermodynamics |
| Volume | 135 |
| DOIs | |
| State | Published - Aug 2019 |
Bibliographical note
Publisher Copyright:© 2019
Keywords
- Acetonitrile
- Binary liquid mixtures
- Preferential solvation
- Self-association
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