Preferential Solvation in two- and in Three-Component Systems

A. Ben-Naim

doi:10.1351/pac199062010025

Preferential Solvation in two- and in Three-Component Systems

A. Ben-Naim^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

225 Scopus citations

Abstract

The concepts of local compositions around a solute and preferential solvaton of a solute are defined in terms of the Kirkwood-Buff integrals. The difference between the local’ and the bulk composition is a measure of the preferential solvation of a solute with respect to the various components of the solvent. A statistical mechanical theory is developed that leads to simple relationships between local compositions and experimentally measurable quantities. These are applied to both two- and three-component systems.

Original language	English
Pages (from-to)	25-34
Number of pages	10
Journal	Pure and Applied Chemistry
Volume	62
Issue number	1
DOIs	https://doi.org/10.1351/pac199062010025
State	Published - Jan 1990

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Preferential Solvation in two- and in Three-Component Systems

Abstract

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