TY - JOUR
T1 - Preferential solvation of silver(I), copper(I) and copper(II) ions in aqueous acetonitrile
AU - Marcus, Yizhak
PY - 1991
Y1 - 1991
N2 - The preferential solvation of Ag+, Cu+ and Cu2+ ions in the mixed solvent water + acetonitrile has been examined on the basis of spectroscopic and other relevant data from the literature and calculated according to the quasi-lattice quasi-chemical method. This study confirms that the monovalent ions are strongly preferentially solvated by the acetonitrile component of the mixtures, whereas the divalent ion is strongly preferentially solvated by the water component.
AB - The preferential solvation of Ag+, Cu+ and Cu2+ ions in the mixed solvent water + acetonitrile has been examined on the basis of spectroscopic and other relevant data from the literature and calculated according to the quasi-lattice quasi-chemical method. This study confirms that the monovalent ions are strongly preferentially solvated by the acetonitrile component of the mixtures, whereas the divalent ion is strongly preferentially solvated by the water component.
UR - http://www.scopus.com/inward/record.url?scp=37049071549&partnerID=8YFLogxK
U2 - 10.1039/DT9910002265
DO - 10.1039/DT9910002265
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AN - SCOPUS:37049071549
SN - 1472-7773
SP - 2265
EP - 2268
JO - Journal of the Chemical Society. Dalton Transactions
JF - Journal of the Chemical Society. Dalton Transactions
IS - 9
ER -