TY - JOUR
T1 - Preparation, crystal structure and raman spectrum of tetrachloro phosphonium tetrachloro-iodate [PCl4] [ICl4]
AU - Shamir, Jacob
AU - Schneider, Shlomo
AU - Bino, Avi
AU - Cohen, Shmuel
PY - 1986/4/1
Y1 - 1986/4/1
N2 - The preparation of [PtCl4] [ICl4] is described. Its structure was determined by both X-ray analysis and Raman spectroscopy. This compound is orthorhombic, space group Imma with a = 12.315(1), b = 16.302(2), c = 12.215(1) Å V = 2452(1) Å3 and Z = 8. The structure was refined by least squares to R = 3.2% using 753 observed refiections. The PtCl4+ cation is tetrahedral with Td symmetry, whereas the two crystallographically independent ICl4- anions are square planar - one with an almost ideal D4h symmetry and the other slightly distorted to a C2v symmetry. The I-Cl distances are in the range of 2.461(4)-2.508(3) Å.
AB - The preparation of [PtCl4] [ICl4] is described. Its structure was determined by both X-ray analysis and Raman spectroscopy. This compound is orthorhombic, space group Imma with a = 12.315(1), b = 16.302(2), c = 12.215(1) Å V = 2452(1) Å3 and Z = 8. The structure was refined by least squares to R = 3.2% using 753 observed refiections. The PtCl4+ cation is tetrahedral with Td symmetry, whereas the two crystallographically independent ICl4- anions are square planar - one with an almost ideal D4h symmetry and the other slightly distorted to a C2v symmetry. The I-Cl distances are in the range of 2.461(4)-2.508(3) Å.
UR - http://www.scopus.com/inward/record.url?scp=4243987039&partnerID=8YFLogxK
U2 - 10.1016/S0020-1693(00)84585-5
DO - 10.1016/S0020-1693(00)84585-5
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AN - SCOPUS:4243987039
SN - 0020-1693
VL - 114
SP - 35
EP - 39
JO - Inorganica Chimica Acta
JF - Inorganica Chimica Acta
IS - 1
ER -