Preparation of methylene-substituted calixarenes

Silvio E. Biali

doi:10.1007/978-3-319-31867-7_4

Preparation of methylene-substituted calixarenes

Silvio E. Biali^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

3 Scopus citations

Abstract

The different synthetic approaches for the preparation of “classical” calixarenes with one, part, or all bridges chemically modified are reviewed. The methods include the cyclization of fragments, the homologous anionic ortho Fries rearrangement, the spirodienone method, the lithiation/alkylation approach, the oxidation of the bridges followed by reaction of the carbonyl units with organolithium reagents, and the bromination of the bridges followed by reaction with nucleophiles.

Original language	English
Title of host publication	Calixarenes and Beyond
Publisher	Springer
Pages	75-93
Number of pages	19
ISBN (Electronic)	9783319318677
ISBN (Print)	9783319318653
DOIs	https://doi.org/10.1007/978-3-319-31867-7_4
State	Published - 1 Jan 2016

Bibliographical note

Publisher Copyright:
© Springer International Publishing Switzerland 2016.

Keywords

Bromination
Calixarenes
Cyclophanes
Oxidation
Synthesis

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10.1007/978-3-319-31867-7_4

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KW - Cyclophanes

KW - Oxidation

KW - Synthesis

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Preparation of methylene-substituted calixarenes

Abstract

Bibliographical note

Keywords

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