Probing CTTS dynamics of Na- in THF: Novel relaxation and polarization effects

Zhaohui Wang; Ophir Shoshana; Sanford Ruhman

doi:10.1007/978-3-642-56546-5_184

Probing CTTS dynamics of Na^- in THF: Novel relaxation and polarization effects

Zhaohui Wang
, Ophir Shoshana
, Sanford Ruhman^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Ultrafast photoselective photolysis of sodide demonstrates for the first time that its CTTS transition dipole is oriented in the solvent, and the related absorption band is inhomogeneously broadened. Continuous evolution of absorption and its anisotropy reflecting solvent dynamics, are observed.

Original language	English
Pages (from-to)	624-626
Number of pages	3
Journal	Springer Series in Chemical Physics
Volume	66
DOIs	https://doi.org/10.1007/978-3-642-56546-5_184
State	Published - 2001

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title = "Probing CTTS dynamics of Na- in THF: Novel relaxation and polarization effects",

abstract = "Ultrafast photoselective photolysis of sodide demonstrates for the first time that its CTTS transition dipole is oriented in the solvent, and the related absorption band is inhomogeneously broadened. Continuous evolution of absorption and its anisotropy reflecting solvent dynamics, are observed.",

author = "Zhaohui Wang and Ophir Shoshana and Sanford Ruhman",

year = "2001",

doi = "10.1007/978-3-642-56546-5\_184",

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T1 - Probing CTTS dynamics of Na- in THF

T2 - Novel relaxation and polarization effects

AU - Wang, Zhaohui

AU - Shoshana, Ophir

AU - Ruhman, Sanford

PY - 2001

Y1 - 2001

N2 - Ultrafast photoselective photolysis of sodide demonstrates for the first time that its CTTS transition dipole is oriented in the solvent, and the related absorption band is inhomogeneously broadened. Continuous evolution of absorption and its anisotropy reflecting solvent dynamics, are observed.

AB - Ultrafast photoselective photolysis of sodide demonstrates for the first time that its CTTS transition dipole is oriented in the solvent, and the related absorption band is inhomogeneously broadened. Continuous evolution of absorption and its anisotropy reflecting solvent dynamics, are observed.

UR - https://www.scopus.com/pages/publications/0035778149

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AN - SCOPUS:0035778149

SN - 0172-6218

VL - 66

SP - 624

EP - 626

JO - Springer Series in Chemical Physics

JF - Springer Series in Chemical Physics

ER -

Probing CTTS dynamics of Na^- in THF: Novel relaxation and polarization effects

Abstract

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