TY - JOUR
T1 - Product state distribution in exoergic chemical reactions and the concept of temperature
AU - Ben-Shaul, A.
AU - Levine, R. D.
AU - Bernstein, R. B.
PY - 1972/8/1
Y1 - 1972/8/1
N2 - The product state distribution in exoergic chemical reactions with respect to any one degree of freedom (translation, rotation or vibration) can be characterized by a temperature. The detailed experiments on the reactions of K + I2, Cl + Hl(Dl) and F + H2(D2) are used as examples. For the latter two systems the products have well-defined (negative) vibrational temperatures, essentially isotopically-invariant.
AB - The product state distribution in exoergic chemical reactions with respect to any one degree of freedom (translation, rotation or vibration) can be characterized by a temperature. The detailed experiments on the reactions of K + I2, Cl + Hl(Dl) and F + H2(D2) are used as examples. For the latter two systems the products have well-defined (negative) vibrational temperatures, essentially isotopically-invariant.
UR - http://www.scopus.com/inward/record.url?scp=0347483541&partnerID=8YFLogxK
U2 - 10.1016/0009-2614(72)80141-6
DO - 10.1016/0009-2614(72)80141-6
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AN - SCOPUS:0347483541
SN - 0009-2614
VL - 15
SP - 160
EP - 164
JO - Chemical Physics Letters
JF - Chemical Physics Letters
IS - 2
ER -