Product state distribution in exoergic chemical reactions and the concept of temperature

A. Ben-Shaul; R. D. Levine; R. B. Bernstein

doi:10.1016/0009-2614(72)80141-6

Product state distribution in exoergic chemical reactions and the concept of temperature

A. Ben-Shaul^*
, R. D. Levine
, R. B. Bernstein

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

40 Scopus citations

Abstract

The product state distribution in exoergic chemical reactions with respect to any one degree of freedom (translation, rotation or vibration) can be characterized by a temperature. The detailed experiments on the reactions of K + I₂, Cl + Hl(Dl) and F + H₂(D₂) are used as examples. For the latter two systems the products have well-defined (negative) vibrational temperatures, essentially isotopically-invariant.

Original language	English
Pages (from-to)	160-164
Number of pages	5
Journal	Chemical Physics Letters
Volume	15
Issue number	2
DOIs	https://doi.org/10.1016/0009-2614(72)80141-6
State	Published - 1 Aug 1972

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title = "Product state distribution in exoergic chemical reactions and the concept of temperature",

abstract = "The product state distribution in exoergic chemical reactions with respect to any one degree of freedom (translation, rotation or vibration) can be characterized by a temperature. The detailed experiments on the reactions of K + I2, Cl + Hl(Dl) and F + H2(D2) are used as examples. For the latter two systems the products have well-defined (negative) vibrational temperatures, essentially isotopically-invariant.",

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AB - The product state distribution in exoergic chemical reactions with respect to any one degree of freedom (translation, rotation or vibration) can be characterized by a temperature. The detailed experiments on the reactions of K + I2, Cl + Hl(Dl) and F + H2(D2) are used as examples. For the latter two systems the products have well-defined (negative) vibrational temperatures, essentially isotopically-invariant.

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Product state distribution in exoergic chemical reactions and the concept of temperature

Abstract

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