TY - JOUR
T1 - Products of the Reaction between Alcohols and Phosphorus Pentoxide
T2 - II. Chromatographic Separation of the Products
AU - Zangen, M.
AU - Marcus, Y.
AU - Bergmann, E. D.
PY - 1968/2/1
Y1 - 1968/2/1
N2 - Various solvents and operating conditions were investigated for paperchromatographic separation of the various esters in the mixture obtained by the reaction P4O10 + 4ROH. Optimum separation was obtained with a propanol-isobutanol-water-ammonia solvent at 10° during 16 hr and perchloric acid-ammonium molybdate developer. These conditions were found to produce complete separation in all investigated mixtures, independently of the nature of the organic chain in the esters. Preparative separation of the various products was obtained by column chromatography, using the same solvent as in paper chromatography on a cellulose-packed column.
AB - Various solvents and operating conditions were investigated for paperchromatographic separation of the various esters in the mixture obtained by the reaction P4O10 + 4ROH. Optimum separation was obtained with a propanol-isobutanol-water-ammonia solvent at 10° during 16 hr and perchloric acid-ammonium molybdate developer. These conditions were found to produce complete separation in all investigated mixtures, independently of the nature of the organic chain in the esters. Preparative separation of the various products was obtained by column chromatography, using the same solvent as in paper chromatography on a cellulose-packed column.
UR - http://www.scopus.com/inward/record.url?scp=84943954488&partnerID=8YFLogxK
U2 - 10.1080/01496396808052203
DO - 10.1080/01496396808052203
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AN - SCOPUS:84943954488
SN - 0037-2366
VL - 3
SP - 1
EP - 9
JO - Separation Science and Technology
JF - Separation Science and Technology
IS - 1
ER -