Pulse radiolysis studies on Br- in aqueous solution: The mechanism of Br2- formation

D. Behar

doi:10.1021/j100657a004

Pulse radiolysis studies on Br^- in aqueous solution: The mechanism of Br₂^- formation

D. Behar^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

28 Scopus citations

Abstract

The reaction of hydroxyl radicals with Br^- has been investigated in the pH regions 9-11.5. The maximum absorption of Br₂^- was followed spectrophotometrically at 365 nm as a function of [Br^-] and [OH^-]. The intermediate species, BrOH^-, is suggested as a precursor in the oxidation mechanism of Br^-.

Original language	English
Pages (from-to)	1815-1818
Number of pages	4
Journal	Journal of Physical Chemistry
Volume	76
Issue number	13
DOIs	https://doi.org/10.1021/j100657a004
State	Published - 1972
Externally published	Yes

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abstract = "The reaction of hydroxyl radicals with Br- has been investigated in the pH regions 9-11.5. The maximum absorption of Br2- was followed spectrophotometrically at 365 nm as a function of [Br-] and [OH-]. The intermediate species, BrOH-, is suggested as a precursor in the oxidation mechanism of Br-.",

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AB - The reaction of hydroxyl radicals with Br- has been investigated in the pH regions 9-11.5. The maximum absorption of Br2- was followed spectrophotometrically at 365 nm as a function of [Br-] and [OH-]. The intermediate species, BrOH-, is suggested as a precursor in the oxidation mechanism of Br-.

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Pulse radiolysis studies on Br^- in aqueous solution: The mechanism of Br₂^- formation

Abstract

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