Abstract
Quasi-bound (resonance) states are present in the continuous spectrum of the Hamiltonian of two coupled Morse oscillators. Two different methods for approximating these as localized states are compared. The algebraic approach is shown to be in very good accord with the other method which is formulated in coordinate space and hence is differential in character. For these highly excited states an intermultiplet mixing term is included in the algebraic Hamiltonian.
Original language | English |
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Pages (from-to) | 255-261 |
Number of pages | 7 |
Journal | Chemical Physics Letters |
Volume | 116 |
Issue number | 4 |
DOIs | |
State | Published - 10 May 1985 |