TY - JOUR
T1 - Reaction of aromatic radical cations with RuCl3·3H2O
AU - Michman, Michael
AU - Oron, Miriam
AU - Schaefer, Hans J.
PY - 2000
Y1 - 2000
N2 - Interactions of RuCl3·3H2O with radical cations of aromatic ethers, 1,4-di-tert-butyl-2,5-dimethoxybenzene, 3,5-di-tert-butyl-1,2-dimethoxybenzene and 2-tert-butyl-1,4-dimethoxybenzene, and with aromatic amines, 2,4,6-tri-tert-butylaniline and N,N,N′,N′-tetramethyl-1,4-phenylenediamine, were observed by voltammetry. ESR and UV spectroscopies were used for the study of the the first two ethers. The effect of RuCl3·3H2O was also examined by controlled potential electrolysis.
AB - Interactions of RuCl3·3H2O with radical cations of aromatic ethers, 1,4-di-tert-butyl-2,5-dimethoxybenzene, 3,5-di-tert-butyl-1,2-dimethoxybenzene and 2-tert-butyl-1,4-dimethoxybenzene, and with aromatic amines, 2,4,6-tri-tert-butylaniline and N,N,N′,N′-tetramethyl-1,4-phenylenediamine, were observed by voltammetry. ESR and UV spectroscopies were used for the study of the the first two ethers. The effect of RuCl3·3H2O was also examined by controlled potential electrolysis.
KW - Anilines
KW - Benzoquinones
KW - Electrocatalysis
KW - Electrooxidation
KW - Ethers
KW - Oxidations
KW - Radical cations
KW - Ruthenium chloride
UR - http://www.scopus.com/inward/record.url?scp=0034340173&partnerID=8YFLogxK
U2 - 10.1135/cccc20000924
DO - 10.1135/cccc20000924
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AN - SCOPUS:0034340173
SN - 0010-0765
VL - 65
SP - 924
EP - 940
JO - Collection of Czechoslovak Chemical Communications
JF - Collection of Czechoslovak Chemical Communications
IS - 6
ER -