TY - JOUR
T1 - Reaction of catalase with ethylhydrogen peroxide
AU - Kremer, Mordechai L.
PY - 1985
Y1 - 1985
N2 - C2H5OOH reacts with catalse in a basically irreversible reaction in the course of which the species called compound (I) is formed and decomposed. The formation of compound (I) is preceded by the formation of a precursor complex which is able to react with a further molecule of C2H5OOH to yield an inactive biperoxy complex. The biperoxy complex causes a diminution of the extent of formation of compound (I) at high [C2H5OOH]. As a consequence, compound (I) can never be formed quantitatively. Some of its physical constants can, nevertheless, be evaluated. Compound (I) with C2H5OOH appears to retain C2H5OH in its structure.
AB - C2H5OOH reacts with catalse in a basically irreversible reaction in the course of which the species called compound (I) is formed and decomposed. The formation of compound (I) is preceded by the formation of a precursor complex which is able to react with a further molecule of C2H5OOH to yield an inactive biperoxy complex. The biperoxy complex causes a diminution of the extent of formation of compound (I) at high [C2H5OOH]. As a consequence, compound (I) can never be formed quantitatively. Some of its physical constants can, nevertheless, be evaluated. Compound (I) with C2H5OOH appears to retain C2H5OH in its structure.
UR - http://www.scopus.com/inward/record.url?scp=33645314671&partnerID=8YFLogxK
U2 - 10.1039/F19858100091
DO - 10.1039/F19858100091
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AN - SCOPUS:33645314671
SN - 0300-9599
VL - 81
SP - 91
EP - 104
JO - Physical Chemistry Chemical Physics
JF - Physical Chemistry Chemical Physics
IS - 1
ER -