TY - JOUR
T1 - Reaction of mercury ions in potassium halide lattices
AU - Ben-Dor, L.
AU - Glasner, A.
AU - Zolotov, S.
PY - 1970/12
Y1 - 1970/12
N2 - Single crystals of potassium halides grown from the melt doped with Hg(II) halides contain mainly Hg(II), and only small amounts of the Hg(I) species formed by partial decomposition. When the alkalihalides are doped with Hg(I), species found in the KI crystal are mainly Hg(I); both Hg(I) and Hg(II) in KBr, but in KCl the monovalent mercury salt decomposes almost completely to its elements. The different species were identified by a study of the spectra of the doped single crystals, before and after additive coloration, and the spectra of the pure alkalihalides coated with the respective mercury halide at room temperature.
AB - Single crystals of potassium halides grown from the melt doped with Hg(II) halides contain mainly Hg(II), and only small amounts of the Hg(I) species formed by partial decomposition. When the alkalihalides are doped with Hg(I), species found in the KI crystal are mainly Hg(I); both Hg(I) and Hg(II) in KBr, but in KCl the monovalent mercury salt decomposes almost completely to its elements. The different species were identified by a study of the spectra of the doped single crystals, before and after additive coloration, and the spectra of the pure alkalihalides coated with the respective mercury halide at room temperature.
UR - http://www.scopus.com/inward/record.url?scp=49849109657&partnerID=8YFLogxK
U2 - 10.1016/0022-4596(70)90050-2
DO - 10.1016/0022-4596(70)90050-2
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AN - SCOPUS:49849109657
SN - 0022-4596
VL - 2
SP - 549
EP - 554
JO - Journal of Solid State Chemistry
JF - Journal of Solid State Chemistry
IS - 4
ER -