REACTIONS IN CHIRAL CRYSTALS. PRINCIPLES GOVERNING ASYMMETRIC SYNTHESIS VIA TOPOCHEMICALLY CONTROLLED SOLID-STATE PHOTODIMERIZATION.

Bernard S. Green; Meir Lahav; G. M.J. Schmidt

REACTIONS IN CHIRAL CRYSTALS. PRINCIPLES GOVERNING ASYMMETRIC SYNTHESIS VIA TOPOCHEMICALLY CONTROLLED SOLID-STATE PHOTODIMERIZATION.

Bernard S. Green^*, Meir Lahav, G. M.J. Schmidt

^*Corresponding author for this work

Faculty of Medicine

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The chemical and crystallographic requirements for utilizing solid-state photodimerization reactions in the medium of chiral crystals to realize asymmetric syntheses have been considered. Asymmetric syntheses are possible from a variety of reactions in the monocomponent or two-component crystals which have been considered and in favorable cases quantitative optical yields are anticipated. These principles can be extended to other reactions including the formation of chiral cyclobutane photopolymers.

Original language	English
Pages (from-to)	187-200
Number of pages	14
Journal	Molecular Crystals and Liquid Crystals
Volume	29
Issue number	3-4
State	Published - 1975

Cite this

@article{72723b75e1314071b607f0013f648004,

title = "REACTIONS IN CHIRAL CRYSTALS. PRINCIPLES GOVERNING ASYMMETRIC SYNTHESIS VIA TOPOCHEMICALLY CONTROLLED SOLID-STATE PHOTODIMERIZATION.",

abstract = "The chemical and crystallographic requirements for utilizing solid-state photodimerization reactions in the medium of chiral crystals to realize asymmetric syntheses have been considered. Asymmetric syntheses are possible from a variety of reactions in the monocomponent or two-component crystals which have been considered and in favorable cases quantitative optical yields are anticipated. These principles can be extended to other reactions including the formation of chiral cyclobutane photopolymers.",

author = "Green, {Bernard S.} and Meir Lahav and Schmidt, {G. M.J.}",

year = "1975",

language = "אנגלית",

volume = "29",

pages = "187--200",

journal = "Molecular Crystals and Liquid Crystals",

issn = "1542-1406",

publisher = "Taylor and Francis Ltd.",

number = "3-4",

}

TY - JOUR

T1 - REACTIONS IN CHIRAL CRYSTALS. PRINCIPLES GOVERNING ASYMMETRIC SYNTHESIS VIA TOPOCHEMICALLY CONTROLLED SOLID-STATE PHOTODIMERIZATION.

AU - Green, Bernard S.

AU - Lahav, Meir

AU - Schmidt, G. M.J.

PY - 1975

Y1 - 1975

N2 - The chemical and crystallographic requirements for utilizing solid-state photodimerization reactions in the medium of chiral crystals to realize asymmetric syntheses have been considered. Asymmetric syntheses are possible from a variety of reactions in the monocomponent or two-component crystals which have been considered and in favorable cases quantitative optical yields are anticipated. These principles can be extended to other reactions including the formation of chiral cyclobutane photopolymers.

AB - The chemical and crystallographic requirements for utilizing solid-state photodimerization reactions in the medium of chiral crystals to realize asymmetric syntheses have been considered. Asymmetric syntheses are possible from a variety of reactions in the monocomponent or two-component crystals which have been considered and in favorable cases quantitative optical yields are anticipated. These principles can be extended to other reactions including the formation of chiral cyclobutane photopolymers.

UR - http://www.scopus.com/inward/record.url?scp=0016427453&partnerID=8YFLogxK

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0016427453

SN - 1542-1406

VL - 29

SP - 187

EP - 200

JO - Molecular Crystals and Liquid Crystals

JF - Molecular Crystals and Liquid Crystals

IS - 3-4

ER -

REACTIONS IN CHIRAL CRYSTALS. PRINCIPLES GOVERNING ASYMMETRIC SYNTHESIS VIA TOPOCHEMICALLY CONTROLLED SOLID-STATE PHOTODIMERIZATION.

Abstract

Other files and links

Fingerprint

Cite this