REACTIONS IN CHIRAL CRYSTALS. PRINCIPLES GOVERNING ASYMMETRIC SYNTHESIS VIA TOPOCHEMICALLY CONTROLLED SOLID-STATE PHOTODIMERIZATION.

Bernard S. Green; Meir Lahav; G. M.J. Schmidt

REACTIONS IN CHIRAL CRYSTALS. PRINCIPLES GOVERNING ASYMMETRIC SYNTHESIS VIA TOPOCHEMICALLY CONTROLLED SOLID-STATE PHOTODIMERIZATION.

Bernard S. Green^*
, Meir Lahav
, G. M.J. Schmidt

^*Corresponding author for this work

Faculty of Medicine

Research output: Contribution to journal › Article › peer-review

37 Scopus citations

Abstract

The chemical and crystallographic requirements for utilizing solid-state photodimerization reactions in the medium of chiral crystals to realize asymmetric syntheses have been considered. Asymmetric syntheses are possible from a variety of reactions in the monocomponent or two-component crystals which have been considered and in favorable cases quantitative optical yields are anticipated. These principles can be extended to other reactions including the formation of chiral cyclobutane photopolymers.

Original language	English
Pages (from-to)	187-200
Number of pages	14
Journal	Molecular Crystals and Liquid Crystals
Volume	29
Issue number	3-4
State	Published - 1975

Cite this

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title = "REACTIONS IN CHIRAL CRYSTALS. PRINCIPLES GOVERNING ASYMMETRIC SYNTHESIS VIA TOPOCHEMICALLY CONTROLLED SOLID-STATE PHOTODIMERIZATION.",

abstract = "The chemical and crystallographic requirements for utilizing solid-state photodimerization reactions in the medium of chiral crystals to realize asymmetric syntheses have been considered. Asymmetric syntheses are possible from a variety of reactions in the monocomponent or two-component crystals which have been considered and in favorable cases quantitative optical yields are anticipated. These principles can be extended to other reactions including the formation of chiral cyclobutane photopolymers.",

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AB - The chemical and crystallographic requirements for utilizing solid-state photodimerization reactions in the medium of chiral crystals to realize asymmetric syntheses have been considered. Asymmetric syntheses are possible from a variety of reactions in the monocomponent or two-component crystals which have been considered and in favorable cases quantitative optical yields are anticipated. These principles can be extended to other reactions including the formation of chiral cyclobutane photopolymers.

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REACTIONS IN CHIRAL CRYSTALS. PRINCIPLES GOVERNING ASYMMETRIC SYNTHESIS VIA TOPOCHEMICALLY CONTROLLED SOLID-STATE PHOTODIMERIZATION.

Abstract

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