Reactions of dicyclopropylacetylene with iron carbonyls

Rae Victor; Varda Usieli; Shalom Sarel

doi:10.1016/S0022-328X(00)92138-7

Reactions of dicyclopropylacetylene with iron carbonyls

Rae Victor^*
, Varda Usieli
, Shalom Sarel

^*Corresponding author for this work

Faculty of Medicine

Research output: Contribution to journal › Article › peer-review

27 Scopus citations

Abstract

Dicyclopropylacetylene has been brought into reaction under photolytic conditions with Fe(CO)₅ and under thermal conditions with Fe₂(CO)₉ and with Fe₃(CO)₁₂. It was possible to obtain primarily monoacetylene adducts or bis(acetylene) adducts by modification of the reaction conditions. In addition to products normally obtained from reactions of acetylenes with iron carbonyls, products derived from cyclopropane ring opening were important. Of particular interest are products which resulted from ring opening and carbonyl insertion to yield cyclopentenone derivatives. Experiments were attempted to show the interrelationships between the various products obtained.

Original language	English
Pages (from-to)	387-399
Number of pages	13
Journal	Journal of Organometallic Chemistry
Volume	129
Issue number	3
DOIs	https://doi.org/10.1016/S0022-328X(00)92138-7
State	Published - 19 Apr 1977

Access to Document

10.1016/S0022-328X(00)92138-7

Cite this

@article{250ef378d8eb428d8fdb979dd4afe62f,

title = "Reactions of dicyclopropylacetylene with iron carbonyls",

abstract = "Dicyclopropylacetylene has been brought into reaction under photolytic conditions with Fe(CO)5 and under thermal conditions with Fe2(CO)9 and with Fe3(CO)12. It was possible to obtain primarily monoacetylene adducts or bis(acetylene) adducts by modification of the reaction conditions. In addition to products normally obtained from reactions of acetylenes with iron carbonyls, products derived from cyclopropane ring opening were important. Of particular interest are products which resulted from ring opening and carbonyl insertion to yield cyclopentenone derivatives. Experiments were attempted to show the interrelationships between the various products obtained.",

author = "Rae Victor and Varda Usieli and Shalom Sarel",

year = "1977",

month = apr,

day = "19",

doi = "10.1016/S0022-328X(00)92138-7",

language = "אנגלית",

volume = "129",

pages = "387--399",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier B.V.",

number = "3",

}

TY - JOUR

T1 - Reactions of dicyclopropylacetylene with iron carbonyls

AU - Victor, Rae

AU - Usieli, Varda

AU - Sarel, Shalom

PY - 1977/4/19

Y1 - 1977/4/19

N2 - Dicyclopropylacetylene has been brought into reaction under photolytic conditions with Fe(CO)5 and under thermal conditions with Fe2(CO)9 and with Fe3(CO)12. It was possible to obtain primarily monoacetylene adducts or bis(acetylene) adducts by modification of the reaction conditions. In addition to products normally obtained from reactions of acetylenes with iron carbonyls, products derived from cyclopropane ring opening were important. Of particular interest are products which resulted from ring opening and carbonyl insertion to yield cyclopentenone derivatives. Experiments were attempted to show the interrelationships between the various products obtained.

AB - Dicyclopropylacetylene has been brought into reaction under photolytic conditions with Fe(CO)5 and under thermal conditions with Fe2(CO)9 and with Fe3(CO)12. It was possible to obtain primarily monoacetylene adducts or bis(acetylene) adducts by modification of the reaction conditions. In addition to products normally obtained from reactions of acetylenes with iron carbonyls, products derived from cyclopropane ring opening were important. Of particular interest are products which resulted from ring opening and carbonyl insertion to yield cyclopentenone derivatives. Experiments were attempted to show the interrelationships between the various products obtained.

UR - https://www.scopus.com/pages/publications/0345860462

U2 - 10.1016/S0022-328X(00)92138-7

DO - 10.1016/S0022-328X(00)92138-7

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:0345860462

SN - 0022-328X

VL - 129

SP - 387

EP - 399

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 3

ER -

Reactions of dicyclopropylacetylene with iron carbonyls

Abstract

Access to Document

Other files and links

Fingerprint

Cite this