Reactions of mercury-like ions in potassium halide lattices

L. Ben-Dor; A. Glasner; S. Zolotov

doi:10.1016/0022-4596(72)90125-9

Reactions of mercury-like ions in potassium halide lattices

L. Ben-Dor^*, A. Glasner, S. Zolotov

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Cadmium and zinc enter the alkali halide matrices as M²⁺ ions and exhibit characteristic absorption bands in the uv. Often these divalent species aggregate to form dimers (and polymers). After additive coloration of the doped single crystals, reduction occurs and monovalent monomers or dimers, and neutral atomary centers are formed. The monovalent dimers exhibit a broad ESR signal with a g value of ∼2.2.

Original language	English
Pages (from-to)	4-10
Number of pages	7
Journal	Journal of Solid State Chemistry
Volume	4
Issue number	1
DOIs	https://doi.org/10.1016/0022-4596(72)90125-9
State	Published - Jan 1972

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title = "Reactions of mercury-like ions in potassium halide lattices",

abstract = "Cadmium and zinc enter the alkali halide matrices as M2+ ions and exhibit characteristic absorption bands in the uv. Often these divalent species aggregate to form dimers (and polymers). After additive coloration of the doped single crystals, reduction occurs and monovalent monomers or dimers, and neutral atomary centers are formed. The monovalent dimers exhibit a broad ESR signal with a g value of ∼2.2.",

author = "L. Ben-Dor and A. Glasner and S. Zolotov",

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AB - Cadmium and zinc enter the alkali halide matrices as M2+ ions and exhibit characteristic absorption bands in the uv. Often these divalent species aggregate to form dimers (and polymers). After additive coloration of the doped single crystals, reduction occurs and monovalent monomers or dimers, and neutral atomary centers are formed. The monovalent dimers exhibit a broad ESR signal with a g value of ∼2.2.

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Reactions of mercury-like ions in potassium halide lattices

Abstract

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