Reactions of methyltris(triarylphosphine)cobalt. I. Formation of biaryls

Michael Michman; Vered R. Kaufman; Sophia Nussbaum

doi:10.1016/S0022-328X(00)83943-1

Reactions of methyltris(triarylphosphine)cobalt. I. Formation of biaryls

Michael Michman^*, Vered R. Kaufman, Sophia Nussbaum

^*Corresponding author for this work

Institute of Chemistry

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Abstract

Methyltris(triarylphosphine)cobalt (Ar₃P)₃CoCH₃, decomposes in solutions of THF, benzene or chlorobenzene to yield biaryls. Coupling to biaryls occurs at the ring carbon originally bonded to phosphorus. Mixed biaryls are obtained from crossover reactions of complexes bearing different triarylphosphine ligands and reactions of complexes with free triarylphosphines.

Original language	English
Pages (from-to)	547-553
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	182
Issue number	4
DOIs	https://doi.org/10.1016/S0022-328X(00)83943-1
State	Published - 18 Dec 1979

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abstract = "Methyltris(triarylphosphine)cobalt (Ar3P)3CoCH3, decomposes in solutions of THF, benzene or chlorobenzene to yield biaryls. Coupling to biaryls occurs at the ring carbon originally bonded to phosphorus. Mixed biaryls are obtained from crossover reactions of complexes bearing different triarylphosphine ligands and reactions of complexes with free triarylphosphines.",

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AB - Methyltris(triarylphosphine)cobalt (Ar3P)3CoCH3, decomposes in solutions of THF, benzene or chlorobenzene to yield biaryls. Coupling to biaryls occurs at the ring carbon originally bonded to phosphorus. Mixed biaryls are obtained from crossover reactions of complexes bearing different triarylphosphine ligands and reactions of complexes with free triarylphosphines.

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Reactions of methyltris(triarylphosphine)cobalt. I. Formation of biaryls

Abstract

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