TY - JOUR
T1 - Reactions of RuCl2(PPh3)3 with carbinols
T2 - Formation of ethers, hydrogen-deuterium exchange, and racemization of optically active alcohols
AU - Sasson, Yoel
AU - Blum, Jochanan
PY - 1974
Y1 - 1974
N2 - RuCl2(PPh3)3 catalyses (a) conversion of tertiary and 'positively' substituted secondary carbinols into ethers, (b) H-D exchange in primary and secondary alcohols, and (c) racemization of optically active alcohols; these reactions confirm the intermediacy of ruthenium alkoxides, and β-hydrogen transfer in the formation of ruthenium hydrides from carbinols.
AB - RuCl2(PPh3)3 catalyses (a) conversion of tertiary and 'positively' substituted secondary carbinols into ethers, (b) H-D exchange in primary and secondary alcohols, and (c) racemization of optically active alcohols; these reactions confirm the intermediacy of ruthenium alkoxides, and β-hydrogen transfer in the formation of ruthenium hydrides from carbinols.
UR - http://www.scopus.com/inward/record.url?scp=37049140721&partnerID=8YFLogxK
U2 - 10.1039/C39740000309
DO - 10.1039/C39740000309
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AN - SCOPUS:37049140721
SN - 0022-4936
SP - 309
EP - 310
JO - Chemical Communications
JF - Chemical Communications
IS - 8
ER -