Real-Time Monitoring of Structural Evolution in Cis-Stilbene Photoisomerization Time-Domain Raman Spectroscopy

Satoshi Takeuchi; Sanford Ruhman; Takao Tsuneda; Mahito Chiba; Tetsuya Taketsugu; Tahei Tahara

doi:10.1007/978-3-540-95946-5_99

Real-Time Monitoring of Structural Evolution in Cis-Stilbene Photoisomerization Time-Domain Raman Spectroscopy

Satoshi Takeuchi^*
, Sanford Ruhman
, Takao Tsuneda
, Mahito Chiba
, Tetsuya Taketsugu
, Tahei Tahara

^*Corresponding author for this work

Institute of Chemistry

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

1 Scopus citations

Abstract

We studied the vibrational structure of reactive S1 cis-stilbene through wavepacket motions generated impulsively at various delay-times. They showed gradual frequency downshift, demonstrating highly anharmonic nature of the excited-state potential and structural evolution with photoisomerization.

Original language	English
Title of host publication	Springer Series in Chemical Physics
Publisher	Springer Science and Business Media Deutschland GmbH
Pages	307-309
Number of pages	3
DOIs	https://doi.org/10.1007/978-3-540-95946-5_99
State	Published - 2009

Publication series

Name	Springer Series in Chemical Physics
Volume	92
ISSN (Print)	0172-6218

Bibliographical note

Publisher Copyright:
© 2009, Springer-Verlag Berlin Heidelberg.

Keywords

Fundamental Output
Picosecond Time Scale
Potential Energy Surface
Solvent Dependence
Vibrational Structure

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10.1007/978-3-540-95946-5_99

Cite this

Takeuchi, S., Ruhman, S., Tsuneda, T., Chiba, M., Taketsugu, T., & Tahara, T. (2009). Real-Time Monitoring of Structural Evolution in Cis-Stilbene Photoisomerization Time-Domain Raman Spectroscopy. In Springer Series in Chemical Physics (pp. 307-309). (Springer Series in Chemical Physics; Vol. 92). Springer Science and Business Media Deutschland GmbH. https://doi.org/10.1007/978-3-540-95946-5_99

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abstract = "We studied the vibrational structure of reactive S1 cis-stilbene through wavepacket motions generated impulsively at various delay-times. They showed gradual frequency downshift, demonstrating highly anharmonic nature of the excited-state potential and structural evolution with photoisomerization.",

keywords = "Fundamental Output, Picosecond Time Scale, Potential Energy Surface, Solvent Dependence, Vibrational Structure",

author = "Satoshi Takeuchi and Sanford Ruhman and Takao Tsuneda and Mahito Chiba and Tetsuya Taketsugu and Tahei Tahara",

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Takeuchi, S, Ruhman, S, Tsuneda, T, Chiba, M, Taketsugu, T & Tahara, T 2009, Real-Time Monitoring of Structural Evolution in Cis-Stilbene Photoisomerization Time-Domain Raman Spectroscopy. in Springer Series in Chemical Physics. Springer Series in Chemical Physics, vol. 92, Springer Science and Business Media Deutschland GmbH, pp. 307-309. https://doi.org/10.1007/978-3-540-95946-5_99

Real-Time Monitoring of Structural Evolution in Cis-Stilbene Photoisomerization Time-Domain Raman Spectroscopy. / Takeuchi, Satoshi; Ruhman, Sanford; Tsuneda, Takao et al.
Springer Series in Chemical Physics. Springer Science and Business Media Deutschland GmbH, 2009. p. 307-309 (Springer Series in Chemical Physics; Vol. 92).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › peer-review

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AU - Tahara, Tahei

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KW - Fundamental Output

KW - Picosecond Time Scale

KW - Potential Energy Surface

KW - Solvent Dependence

KW - Vibrational Structure

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Real-Time Monitoring of Structural Evolution in Cis-Stilbene Photoisomerization Time-Domain Raman Spectroscopy

Abstract

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Bibliographical note

Keywords

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