Recent Developments in the Stereochemistry of Cyclopropane Ring Opening

S. Sarel; J. Yovell; M. Sarel‐Imber

doi:10.1002/anie.196805771

Recent Developments in the Stereochemistry of Cyclopropane Ring Opening

S. Sarel, J. Yovell, M. Sarel‐Imber^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

101 Scopus citations

Abstract

This review article deals with the stereochemistry of the following ring opening reactions: 1. Homoallylic rearrangement of secondary and tertiary cyclopropyl alcohols in the presence of electrophilic reagents, 2. The addition of carboxylic acids to vinylcyclopropanes, 3. The thermal rearrangement of vinylcyclopropanes into cyclopentenes. An account is also given of the NMR spectroscopic determination of the conformations of substituted vinylcyclopropanes.

Original language	English
Pages (from-to)	577-588
Number of pages	12
Journal	Angewandte Chemie - International Edition
Volume	7
Issue number	8
DOIs	https://doi.org/10.1002/anie.196805771
State	Published - Aug 1968

Keywords

Cyclopropane ring opening
Ring opening
Stereochemistry

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10.1002/anie.196805771

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abstract = "This review article deals with the stereochemistry of the following ring opening reactions: 1. Homoallylic rearrangement of secondary and tertiary cyclopropyl alcohols in the presence of electrophilic reagents, 2. The addition of carboxylic acids to vinylcyclopropanes, 3. The thermal rearrangement of vinylcyclopropanes into cyclopentenes. An account is also given of the NMR spectroscopic determination of the conformations of substituted vinylcyclopropanes.",

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author = "S. Sarel and J. Yovell and M. Sarel‐Imber",

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Recent Developments in the Stereochemistry of Cyclopropane Ring Opening

Abstract

Keywords

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