Reduction of [Cp2*Mo2O5] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-proprionato(2-)-bridged molybdenum(IV) compound

Chiara Dinoi; Petr Prikhodchenko; Funda Demirhan; Jenny Gun; Ovadia Lev; Jean Claude Daran; Rinaldo Poli

doi:10.1016/j.jorganchem.2007.02.046

Reduction of [Cp₂^*Mo₂O₅] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-proprionato(2-)-bridged molybdenum(IV) compound

Chiara Dinoi, Petr Prikhodchenko, Funda Demirhan, Jenny Gun, Ovadia Lev, Jean Claude Daran, Rinaldo Poli^*

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Short survey › peer-review

6 Scopus citations

Abstract

Reaction of Cp₂^*Mo₂O₅ with HSCH₂CH₂COOH in acidic (by CF₃COOH) 50:50 MeOH-H₂O solvent at room temperature yields compound Cp₂^*Mo₂(μ-O)(μ-SCH₂CH₂CO₂)₂, a dinuclear diamagnetic Mo^IV compound with a two-leg-sharing bis(four-legged piano stool) structure and a Mo-Mo distance of 2.6833(6) Å. A reaction monitoring by ESI MS shows the formation of an intermediate 18 mass units heavier, interpreted as a dihydroxo analogue. Electrochemistry shows a reversible, pH independent oxidation process and an irreversible, pH-dependent reduction process. Contrary to a recently published analogous reaction with the closely related HSCH₂COOH substrate, this process does not lead to C-S bond cleavage.

Original language	English
Pages (from-to)	2599-2605
Number of pages	7
Journal	Journal of Organometallic Chemistry
Volume	692
Issue number	12
DOIs	https://doi.org/10.1016/j.jorganchem.2007.02.046
State	Published - 15 May 2007

Bibliographical note

Funding Information:
We are grateful to the European Commission for funding of this work through the AQUACHEM Research Training Network (Project No. MRTN-CT-2003-503864). Supplemental support by a Bosphorus bilateral Programme of Integrated Actions, co-sponsored by French Ministry of Foreign Affairs in France and by TUBITAK in Turkey (TBAG-U/142(105T265)) is also gratefully acknowledged. The Israeli group is grateful to the Israel Science foundation for support.

Keywords

Alkylsulfido ligands
Aqueous organometallic chemistry
Carboxylato ligands
Molybdenum
Pentamethylcyclopentadienyl ligands

Access to Document

10.1016/j.jorganchem.2007.02.046

Cite this

Dinoi, C., Prikhodchenko, P., Demirhan, F., Gun, J., Lev, O., Daran, J. C., & Poli, R. (2007). Reduction of [Cp₂^*Mo₂O₅] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-proprionato(2-)-bridged molybdenum(IV) compound. Journal of Organometallic Chemistry, 692(12), 2599-2605. https://doi.org/10.1016/j.jorganchem.2007.02.046

@article{7c5785d99b4c4920850077936330d63a,

title = "Reduction of [Cp2*Mo2O5] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-proprionato(2-)-bridged molybdenum(IV) compound",

abstract = "Reaction of Cp2*Mo2O5 with HSCH2CH2COOH in acidic (by CF3COOH) 50:50 MeOH-H2O solvent at room temperature yields compound Cp2*Mo2(μ-O)(μ-SCH2CH2CO2)2, a dinuclear diamagnetic MoIV compound with a two-leg-sharing bis(four-legged piano stool) structure and a Mo-Mo distance of 2.6833(6) {\AA}. A reaction monitoring by ESI MS shows the formation of an intermediate 18 mass units heavier, interpreted as a dihydroxo analogue. Electrochemistry shows a reversible, pH independent oxidation process and an irreversible, pH-dependent reduction process. Contrary to a recently published analogous reaction with the closely related HSCH2COOH substrate, this process does not lead to C-S bond cleavage.",

keywords = "Alkylsulfido ligands, Aqueous organometallic chemistry, Carboxylato ligands, Molybdenum, Pentamethylcyclopentadienyl ligands",

author = "Chiara Dinoi and Petr Prikhodchenko and Funda Demirhan and Jenny Gun and Ovadia Lev and Daran, {Jean Claude} and Rinaldo Poli",

note = "Funding Information: We are grateful to the European Commission for funding of this work through the AQUACHEM Research Training Network (Project No. MRTN-CT-2003-503864). Supplemental support by a Bosphorus bilateral Programme of Integrated Actions, co-sponsored by French Ministry of Foreign Affairs in France and by TUBITAK in Turkey (TBAG-U/142(105T265)) is also gratefully acknowledged. The Israeli group is grateful to the Israel Science foundation for support. ",

year = "2007",

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doi = "10.1016/j.jorganchem.2007.02.046",

language = "אנגלית",

volume = "692",

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Dinoi, C, Prikhodchenko, P, Demirhan, F, Gun, J, Lev, O, Daran, JC & Poli, R 2007, 'Reduction of [Cp₂^*Mo₂O₅] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-proprionato(2-)-bridged molybdenum(IV) compound', Journal of Organometallic Chemistry, vol. 692, no. 12, pp. 2599-2605. https://doi.org/10.1016/j.jorganchem.2007.02.046

Reduction of [Cp₂^*Mo₂O₅] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-proprionato(2-)-bridged molybdenum(IV) compound. / Dinoi, Chiara; Prikhodchenko, Petr; Demirhan, Funda et al.
In: Journal of Organometallic Chemistry, Vol. 692, No. 12, 15.05.2007, p. 2599-2605.

Research output: Contribution to journal › Short survey › peer-review

TY - JOUR

T1 - Reduction of [Cp2*Mo2O5] by mercaptopropionic acid in an aqueous medium. Isolation and characterization of a dinuclear oxo- and 3-sulfido-proprionato(2-)-bridged molybdenum(IV) compound

AU - Dinoi, Chiara

AU - Prikhodchenko, Petr

AU - Demirhan, Funda

AU - Gun, Jenny

AU - Lev, Ovadia

AU - Daran, Jean Claude

AU - Poli, Rinaldo

N1 - Funding Information: We are grateful to the European Commission for funding of this work through the AQUACHEM Research Training Network (Project No. MRTN-CT-2003-503864). Supplemental support by a Bosphorus bilateral Programme of Integrated Actions, co-sponsored by French Ministry of Foreign Affairs in France and by TUBITAK in Turkey (TBAG-U/142(105T265)) is also gratefully acknowledged. The Israeli group is grateful to the Israel Science foundation for support.

PY - 2007/5/15

Y1 - 2007/5/15

N2 - Reaction of Cp2*Mo2O5 with HSCH2CH2COOH in acidic (by CF3COOH) 50:50 MeOH-H2O solvent at room temperature yields compound Cp2*Mo2(μ-O)(μ-SCH2CH2CO2)2, a dinuclear diamagnetic MoIV compound with a two-leg-sharing bis(four-legged piano stool) structure and a Mo-Mo distance of 2.6833(6) Å. A reaction monitoring by ESI MS shows the formation of an intermediate 18 mass units heavier, interpreted as a dihydroxo analogue. Electrochemistry shows a reversible, pH independent oxidation process and an irreversible, pH-dependent reduction process. Contrary to a recently published analogous reaction with the closely related HSCH2COOH substrate, this process does not lead to C-S bond cleavage.

AB - Reaction of Cp2*Mo2O5 with HSCH2CH2COOH in acidic (by CF3COOH) 50:50 MeOH-H2O solvent at room temperature yields compound Cp2*Mo2(μ-O)(μ-SCH2CH2CO2)2, a dinuclear diamagnetic MoIV compound with a two-leg-sharing bis(four-legged piano stool) structure and a Mo-Mo distance of 2.6833(6) Å. A reaction monitoring by ESI MS shows the formation of an intermediate 18 mass units heavier, interpreted as a dihydroxo analogue. Electrochemistry shows a reversible, pH independent oxidation process and an irreversible, pH-dependent reduction process. Contrary to a recently published analogous reaction with the closely related HSCH2COOH substrate, this process does not lead to C-S bond cleavage.

KW - Alkylsulfido ligands

KW - Aqueous organometallic chemistry

KW - Carboxylato ligands

KW - Molybdenum

KW - Pentamethylcyclopentadienyl ligands

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