Reduction of pyracylene by alkali metals: Mechanism and formation of aggregates

Gil Zilber; Vladimir Rozenshtein; Ari Ayalon; Haim Levanon; Mordecai Rabinovitz; Lawrence T. Scott; Hope B. Warren; Gaby Persy; Jakob Wirz

doi:10.1163/156856796X00511

Reduction of pyracylene by alkali metals: Mechanism and formation of aggregates

Gil Zilber
, Vladimir Rozenshtein
, Ari Ayalon
, Haim Levanon^*
, Mordecai Rabinovitz
, Lawrence T. Scott
, Hope B. Warren
, Gaby Persy
, Jakob Wirz

^*Corresponding author for this work

The Institute of Applied Physics

Research output: Contribution to journal › Article › peer-review

2 Scopus citations

Abstract

Five reaction stages have been identified in the reduction of pyracylene to its dianion. The same stages were also observed in the photochemical oxidation starting with the dianion. The formation of dimers of anions and of mixed valence aggregates is discussed.

Original language	English
Pages (from-to)	839-854
Number of pages	16
Journal	Research on Chemical Intermediates
Volume	22
Issue number	9
DOIs	https://doi.org/10.1163/156856796X00511
State	Published - 1996

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title = "Reduction of pyracylene by alkali metals: Mechanism and formation of aggregates",

abstract = "Five reaction stages have been identified in the reduction of pyracylene to its dianion. The same stages were also observed in the photochemical oxidation starting with the dianion. The formation of dimers of anions and of mixed valence aggregates is discussed.",

author = "Gil Zilber and Vladimir Rozenshtein and Ari Ayalon and Haim Levanon and Mordecai Rabinovitz and Scott, \{Lawrence T.\} and Warren, \{Hope B.\} and Gaby Persy and Jakob Wirz",

year = "1996",

doi = "10.1163/156856796X00511",

language = "אנגלית",

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pages = "839--854",

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T2 - Mechanism and formation of aggregates

AU - Zilber, Gil

AU - Rozenshtein, Vladimir

AU - Ayalon, Ari

AU - Levanon, Haim

AU - Rabinovitz, Mordecai

AU - Scott, Lawrence T.

AU - Warren, Hope B.

AU - Persy, Gaby

AU - Wirz, Jakob

PY - 1996

Y1 - 1996

N2 - Five reaction stages have been identified in the reduction of pyracylene to its dianion. The same stages were also observed in the photochemical oxidation starting with the dianion. The formation of dimers of anions and of mixed valence aggregates is discussed.

AB - Five reaction stages have been identified in the reduction of pyracylene to its dianion. The same stages were also observed in the photochemical oxidation starting with the dianion. The formation of dimers of anions and of mixed valence aggregates is discussed.

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AN - SCOPUS:5844306713

SN - 0922-6168

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SP - 839

EP - 854

JO - Research on Chemical Intermediates

JF - Research on Chemical Intermediates

IS - 9

ER -

Reduction of pyracylene by alkali metals: Mechanism and formation of aggregates

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