Relaxation dynamics in glycerol-water mixtures. 2. Mesoscopic feature in water rich mixtures

Yoshihito Hayashi; Alexander Puzenko; Igal Balin; Yaroslav E. Ryabov; Yuri Feldman

doi:10.1021/jp050425d

Relaxation dynamics in glycerol-water mixtures. 2. Mesoscopic feature in water rich mixtures

Yoshihito Hayashi
, Alexander Puzenko
, Igal Balin
, Yaroslav E. Ryabov
, Yuri Feldman^*

^*Corresponding author for this work

The Institute of Applied Physics

Research output: Contribution to journal › Article › peer-review

81 Scopus citations

Abstract

The relaxation dynamics of water-rich glycerol-water mixtures is studied by broadband dielectric spectroscopy (BDS) at 173-323 K and differential scanning calorimetry (DSC) at 138-313 K. These data indicate the existence of the critical concentration of 40 mol% glycerol. In the studied temperature range for water-rich glycerol mixtures, the two states of water (ice and interfacial water) are observed in addition to water in the mesoscopic 40 mol% glycerol-water domains. The possible kinetics of water exchange between different water states is discussed in order to explain the mechanism of the broad melting behavior observed by DSC.

Original language	English
Pages (from-to)	9174-9177
Number of pages	4
Journal	Journal of Physical Chemistry B
Volume	109
Issue number	18
DOIs	https://doi.org/10.1021/jp050425d
State	Published - 12 May 2005

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title = "Relaxation dynamics in glycerol-water mixtures. 2. Mesoscopic feature in water rich mixtures",

abstract = "The relaxation dynamics of water-rich glycerol-water mixtures is studied by broadband dielectric spectroscopy (BDS) at 173-323 K and differential scanning calorimetry (DSC) at 138-313 K. These data indicate the existence of the critical concentration of 40 mol\% glycerol. In the studied temperature range for water-rich glycerol mixtures, the two states of water (ice and interfacial water) are observed in addition to water in the mesoscopic 40 mol\% glycerol-water domains. The possible kinetics of water exchange between different water states is discussed in order to explain the mechanism of the broad melting behavior observed by DSC.",

author = "Yoshihito Hayashi and Alexander Puzenko and Igal Balin and Ryabov, \{Yaroslav E.\} and Yuri Feldman",

year = "2005",

month = may,

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doi = "10.1021/jp050425d",

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AU - Hayashi, Yoshihito

AU - Puzenko, Alexander

AU - Balin, Igal

AU - Ryabov, Yaroslav E.

AU - Feldman, Yuri

PY - 2005/5/12

Y1 - 2005/5/12

N2 - The relaxation dynamics of water-rich glycerol-water mixtures is studied by broadband dielectric spectroscopy (BDS) at 173-323 K and differential scanning calorimetry (DSC) at 138-313 K. These data indicate the existence of the critical concentration of 40 mol% glycerol. In the studied temperature range for water-rich glycerol mixtures, the two states of water (ice and interfacial water) are observed in addition to water in the mesoscopic 40 mol% glycerol-water domains. The possible kinetics of water exchange between different water states is discussed in order to explain the mechanism of the broad melting behavior observed by DSC.

AB - The relaxation dynamics of water-rich glycerol-water mixtures is studied by broadband dielectric spectroscopy (BDS) at 173-323 K and differential scanning calorimetry (DSC) at 138-313 K. These data indicate the existence of the critical concentration of 40 mol% glycerol. In the studied temperature range for water-rich glycerol mixtures, the two states of water (ice and interfacial water) are observed in addition to water in the mesoscopic 40 mol% glycerol-water domains. The possible kinetics of water exchange between different water states is discussed in order to explain the mechanism of the broad melting behavior observed by DSC.

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JO - Journal of Physical Chemistry B

JF - Journal of Physical Chemistry B

IS - 18

ER -

Relaxation dynamics in glycerol-water mixtures. 2. Mesoscopic feature in water rich mixtures

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