Research on the chemistry of phenoxazines - 12. Reaction of 2-substituted 3-phenoxazinones with thiophenols

G. B. Afanas'eva; T. S. Viktorova; I. Ya Postovskii; I. I. Bil'kis; S. M. Shein

doi:10.1007/BF00475386

Research on the chemistry of phenoxazines - 12. Reaction of 2-substituted 3-phenoxazinones with thiophenols

G. B. Afanas'eva^*
, T. S. Viktorova
, I. Ya Postovskii
, I. I. Bil'kis
, S. M. Shein

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

Abstract

A third reaction center in the phenoxazinone molecule, viz., the 9 position in the benzenoid ring, was observed for the first time in the reaction of 3-phenoxazinone and its 2-hydroxy and 2-ethoxy derivatives with p-thiocresol. In conformity with this, 2,7,9-triarylthio derivatives are formed along with the usual 2,7-disubstituted derivatives of 3-phenoxazinone. The structures of the compounds obtained were confirmed by the PMR and EPR spectra and a number of chemical transformations.

Original language	English
Pages (from-to)	32-36
Number of pages	5
Journal	Chemistry of Heterocyclic Compounds
Volume	16
Issue number	1
DOIs	https://doi.org/10.1007/BF00475386
State	Published - Jan 1980
Externally published	Yes

Access to Document

10.1007/BF00475386

Cite this

@article{ec5b2f346cc349d8bbfc28c6db10165d,

title = "Research on the chemistry of phenoxazines - 12. Reaction of 2-substituted 3-phenoxazinones with thiophenols",

abstract = "A third reaction center in the phenoxazinone molecule, viz., the 9 position in the benzenoid ring, was observed for the first time in the reaction of 3-phenoxazinone and its 2-hydroxy and 2-ethoxy derivatives with p-thiocresol. In conformity with this, 2,7,9-triarylthio derivatives are formed along with the usual 2,7-disubstituted derivatives of 3-phenoxazinone. The structures of the compounds obtained were confirmed by the PMR and EPR spectra and a number of chemical transformations.",

author = "Afanas'eva, \{G. B.\} and Viktorova, \{T. S.\} and Postovskii, \{I. Ya\} and Bil'kis, \{I. I.\} and Shein, \{S. M.\}",

year = "1980",

month = jan,

doi = "10.1007/BF00475386",

language = "אנגלית",

volume = "16",

pages = "32--36",

journal = "Chemistry of Heterocyclic Compounds",

issn = "0009-3122",

publisher = "Springer",

number = "1",

}

TY - JOUR

T1 - Research on the chemistry of phenoxazines - 12. Reaction of 2-substituted 3-phenoxazinones with thiophenols

AU - Afanas'eva, G. B.

AU - Viktorova, T. S.

AU - Postovskii, I. Ya

AU - Bil'kis, I. I.

AU - Shein, S. M.

PY - 1980/1

Y1 - 1980/1

N2 - A third reaction center in the phenoxazinone molecule, viz., the 9 position in the benzenoid ring, was observed for the first time in the reaction of 3-phenoxazinone and its 2-hydroxy and 2-ethoxy derivatives with p-thiocresol. In conformity with this, 2,7,9-triarylthio derivatives are formed along with the usual 2,7-disubstituted derivatives of 3-phenoxazinone. The structures of the compounds obtained were confirmed by the PMR and EPR spectra and a number of chemical transformations.

AB - A third reaction center in the phenoxazinone molecule, viz., the 9 position in the benzenoid ring, was observed for the first time in the reaction of 3-phenoxazinone and its 2-hydroxy and 2-ethoxy derivatives with p-thiocresol. In conformity with this, 2,7,9-triarylthio derivatives are formed along with the usual 2,7-disubstituted derivatives of 3-phenoxazinone. The structures of the compounds obtained were confirmed by the PMR and EPR spectra and a number of chemical transformations.

UR - https://www.scopus.com/pages/publications/34250258002

U2 - 10.1007/BF00475386

DO - 10.1007/BF00475386

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:34250258002

SN - 0009-3122

VL - 16

SP - 32

EP - 36

JO - Chemistry of Heterocyclic Compounds

JF - Chemistry of Heterocyclic Compounds

IS - 1

ER -

Research on the chemistry of phenoxazines - 12. Reaction of 2-substituted 3-phenoxazinones with thiophenols

Abstract

Access to Document

Other files and links

Fingerprint

Cite this