Reversible ion-pair extraction in a biphasic system. application in transition metal-catalyzed isomerization of allylic compounds

Yoel Sasson; Amikam Zoran; Jochanan Blum

doi:10.1016/0304-5102(81)87017-4

Reversible ion-pair extraction in a biphasic system. application in transition metal-catalyzed isomerization of allylic compounds

Yoel Sasson^*, Amikam Zoran, Jochanan Blum

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

78 Scopus citations

Abstract

A two-liquid-phase catalysis is described in which aqueous metal halides of Group VIII are used for the isomerization of water-insoluble allylic compounds. With the aid of quaternary ammonium or phosphonium salts, the metal catalyst is extracted into the reagent-containing phase and returned to the aqueous layer by lipophilic anions upon completion of the catalytic process.

Original language	English
Pages (from-to)	293-300
Number of pages	8
Journal	Journal of Molecular Catalysis
Volume	11
Issue number	2-3
DOIs	https://doi.org/10.1016/0304-5102(81)87017-4
State	Published - 1981

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10.1016/0304-5102(81)87017-4

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title = "Reversible ion-pair extraction in a biphasic system. application in transition metal-catalyzed isomerization of allylic compounds",

abstract = "A two-liquid-phase catalysis is described in which aqueous metal halides of Group VIII are used for the isomerization of water-insoluble allylic compounds. With the aid of quaternary ammonium or phosphonium salts, the metal catalyst is extracted into the reagent-containing phase and returned to the aqueous layer by lipophilic anions upon completion of the catalytic process.",

author = "Yoel Sasson and Amikam Zoran and Jochanan Blum",

year = "1981",

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T1 - Reversible ion-pair extraction in a biphasic system. application in transition metal-catalyzed isomerization of allylic compounds

AU - Sasson, Yoel

AU - Zoran, Amikam

AU - Blum, Jochanan

PY - 1981

Y1 - 1981

N2 - A two-liquid-phase catalysis is described in which aqueous metal halides of Group VIII are used for the isomerization of water-insoluble allylic compounds. With the aid of quaternary ammonium or phosphonium salts, the metal catalyst is extracted into the reagent-containing phase and returned to the aqueous layer by lipophilic anions upon completion of the catalytic process.

AB - A two-liquid-phase catalysis is described in which aqueous metal halides of Group VIII are used for the isomerization of water-insoluble allylic compounds. With the aid of quaternary ammonium or phosphonium salts, the metal catalyst is extracted into the reagent-containing phase and returned to the aqueous layer by lipophilic anions upon completion of the catalytic process.

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AN - SCOPUS:0019560370

SN - 0304-5102

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SP - 293

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JO - Journal of Molecular Catalysis

JF - Journal of Molecular Catalysis

IS - 2-3

ER -

Reversible ion-pair extraction in a biphasic system. application in transition metal-catalyzed isomerization of allylic compounds

Abstract

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