TY - JOUR
T1 - Rigorous derivation of the long-time asymptotics for reversible binding
AU - Gopich, Irina V.
AU - Agmon, Noam
PY - 2000
Y1 - 2000
N2 - Using an iterative solution in Laplace-Fourier space, we supply a rigorous mathematical proof for the long-time asymptotics of reversible binding in one dimension. The asymptotic power law and its concentration dependent prefactor result from diffusional and many-body effects which, unlike for the corresponding irreversible reaction and in classical chemical kinetics, play a dominant role in shaping the approach to equilibrium.
AB - Using an iterative solution in Laplace-Fourier space, we supply a rigorous mathematical proof for the long-time asymptotics of reversible binding in one dimension. The asymptotic power law and its concentration dependent prefactor result from diffusional and many-body effects which, unlike for the corresponding irreversible reaction and in classical chemical kinetics, play a dominant role in shaping the approach to equilibrium.
UR - http://www.scopus.com/inward/record.url?scp=0001569028&partnerID=8YFLogxK
U2 - 10.1103/PhysRevLett.84.2730
DO - 10.1103/PhysRevLett.84.2730
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AN - SCOPUS:0001569028
SN - 0031-9007
VL - 84
SP - 2730
EP - 2733
JO - Physical Review Letters
JF - Physical Review Letters
IS - 12
ER -