Rotational state dependence of the reactivity of oriented symmetric top molecules

R. D. Levine; R. B. Bernstein

doi:10.1016/0009-2614(86)80685-6

Rotational state dependence of the reactivity of oriented symmetric top molecules

R. D. Levine^*
, R. B. Bernstein

^*Corresponding author for this work

Institute of Chemistry

Research output: Contribution to journal › Article › peer-review

10 Scopus citations

Abstract

Extending the angle-dependent line-of-centers model originally developed to treat the orientation dependence of atom-molecule reaction cross sections, it is possible to predict the JKM dependence of the reactivity of rotationally state-selected, oriented symmetric top molecules in collision with spherically symmetric co-reagents. In a certain well-defined limit the cross section depends only upon the characteristic quantum number combination KM/(J²+J), the average orientation of the symmetric top.

Original language	English
Pages (from-to)	11-15
Number of pages	5
Journal	Chemical Physics Letters
Volume	132
Issue number	1
DOIs	https://doi.org/10.1016/0009-2614(86)80685-6
State	Published - 28 Nov 1986

Access to Document

10.1016/0009-2614(86)80685-6

Cite this

@article{77b65ad60f574745b257d11157844b03,

title = "Rotational state dependence of the reactivity of oriented symmetric top molecules",

abstract = "Extending the angle-dependent line-of-centers model originally developed to treat the orientation dependence of atom-molecule reaction cross sections, it is possible to predict the JKM dependence of the reactivity of rotationally state-selected, oriented symmetric top molecules in collision with spherically symmetric co-reagents. In a certain well-defined limit the cross section depends only upon the characteristic quantum number combination KM/(J2+J), the average orientation of the symmetric top.",

author = "Levine, \{R. D.\} and Bernstein, \{R. B.\}",

year = "1986",

month = nov,

day = "28",

doi = "10.1016/0009-2614(86)80685-6",

language = "אנגלית",

volume = "132",

pages = "11--15",

journal = "Chemical Physics Letters",

issn = "0009-2614",

publisher = "Elsevier B.V.",

number = "1",

}

TY - JOUR

T1 - Rotational state dependence of the reactivity of oriented symmetric top molecules

AU - Levine, R. D.

AU - Bernstein, R. B.

PY - 1986/11/28

Y1 - 1986/11/28

N2 - Extending the angle-dependent line-of-centers model originally developed to treat the orientation dependence of atom-molecule reaction cross sections, it is possible to predict the JKM dependence of the reactivity of rotationally state-selected, oriented symmetric top molecules in collision with spherically symmetric co-reagents. In a certain well-defined limit the cross section depends only upon the characteristic quantum number combination KM/(J2+J), the average orientation of the symmetric top.

AB - Extending the angle-dependent line-of-centers model originally developed to treat the orientation dependence of atom-molecule reaction cross sections, it is possible to predict the JKM dependence of the reactivity of rotationally state-selected, oriented symmetric top molecules in collision with spherically symmetric co-reagents. In a certain well-defined limit the cross section depends only upon the characteristic quantum number combination KM/(J2+J), the average orientation of the symmetric top.

UR - https://www.scopus.com/pages/publications/5244320570

U2 - 10.1016/0009-2614(86)80685-6

DO - 10.1016/0009-2614(86)80685-6

M3 - ???researchoutput.researchoutputtypes.contributiontojournal.article???

AN - SCOPUS:5244320570

SN - 0009-2614

VL - 132

SP - 11

EP - 15

JO - Chemical Physics Letters

JF - Chemical Physics Letters

IS - 1

ER -

Rotational state dependence of the reactivity of oriented symmetric top molecules

Abstract

Access to Document

Other files and links

Fingerprint

Cite this